1-Bromoadamantano, 99 %, Thermo Scientific Chemicals

Name: 1-Bromoadamantano, 99 %, Thermo Scientific Chemicals
SKU: A14893.14

CAS: 768-90-1 | C10H15Br | 215.134 g/mol

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25 g

100 g

Número de catálogo A14893.14

también denominado A14893-14

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Cantidad:

25 g

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Identificadores químicos

CAS768-90-1

IUPAC Name1-bromoadamantane

Molecular FormulaC10H15Br

InChI KeyVQHPRVYDKRESCL-UHFFFAOYSA-N

SMILESBrC12CC3CC(CC(C3)C1)C2

Especificaciones Specification Sheet

Hoja de especificaciones

Appearance (Color)White to cream to yellow to pale orange to orange

FormCrystals or powder or crystalline powder

Assay (GC)≥98.5%

Melting Point (clear melt)115.0-121.0°C

1-Bromoadamantane is an important intermediate, used in synthesizing medicines and new materials etc.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Aplicaciones
El 1-bromoadamantano es un importante intermediario que se utiliza en la síntesis de medicamentos y nuevos materiales, etc.

Solubilidad
Es soluble en disolventes orgánicos e insoluble en agua.

Notas
Almacenar en lugar fresco. Mantenga el recipiente bien cerrado en un lugar seco y bien ventilado. Sensible a la humedad. Mantener alejado de agentes oxidantes fuertes.

RUO – Research Use Only

General References:

SL Regen .; JJ Besse .; J McLick. Solid-phase cosolvents. Triphase catalytic hydrolysis of 1-bromoadamantane. Journal of the American Chemical. 1979 101, (1), 116-120.
SL Regen.; L Dulak. Solid-phase cosolvents. Journal of the American Chemical society. 197799, (2), 623-625.
Reduction with Tri-n-butyl tin hydride, A13298, generates the 1-adamantyl radical which, e.g. adds to Michael acceptors in good yield: J. Org. Chem., 53, 1285 (1988).
With activated Ca metal (prepared from CaBr₂ and Li biphenylide), forms an organocalcium reagent which reacts with ketones to give tertiary alcohols; the preparation and reactivity of these intermediates is discussed: Org. Synth. Coll., 9, 9 (1998).
Undergoes Heck-type coupling with styrenes and arenes, catalyzed by Pd on carbon: Synthesis, 148 (1998).