Thermo Scientific Chemicals

Nitrosonium tetrafluoroborate, 98%, Thermo Scientific Chemicals

Catalog number: A15806.04
2 g, Each
Thermo Scientific Chemicals

Nitrosonium tetrafluoroborate, 98%, Thermo Scientific Chemicals

Catalog number: A15806.04
2 g, Each
Quantity
Catalog number: A15806.04
also known as A15806-04
Price (USD)
Quantity
-

Chemical Identifiers

CAS
14635-75-7
IUPAC Name
dioxoamine; tetrafluoroboranuide
Molecular Formula
BF4HNO2
InChI Key
XYRQURYIJKJVSF-UHFFFAOYSA-N
SMILES
[O-][NH+]=O.F[B-](F)(F)F
Appearance (Color)
White
Elemental Analysis
B: 9.02-9.49% (Theory: 9.26%)
Form
Crystals or powder or crystalline powder
Assay (unspecified)
≥97.5%

Description

Nitrosonium tetrafluoroborate is a nitrosating agent and oxidizer used in organic synthesis. It is also used to convert arylamines directly to diazonium tetrafluoroborates, which undergo the Balz-Schiemann reaction in situ to give high yields of aryl fluorides. Further, it is used as a catalyst for iodination of aromatics by iodide ion with air as oxidant, conversion of secondary amines to nitrosamines and in deamination of primary amides. It is involved in the conversion of arylhydrazines to azides. In addition to this, it reacts with ferrocene to prepare ferrocenium tetrafluoroborate.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Nitrosonium tetrafluoroborate is a nitrosating agent and oxidizer used in organic synthesis. It is also used to convert arylamines directly to diazonium tetrafluoroborates, which undergo the Balz-Schiemann reaction in situ to give high yields of aryl fluorides. Further, it is used as a catalyst for iodination of aromatics by iodide ion with air as oxidant, conversion of secondary amines to nitrosamines and in deamination of primary amides. It is involved in the conversion of arylhydrazines to azides. In addition to this, it reacts with ferrocene to prepare ferrocenium tetrafluoroborate.

Solubility
Soluble in acetonitrile.

Notes
Hygroscopic. Air and moisture sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with acids and amines.
RUO – Research Use Only

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