Tetrahydrothiophene 1-oxide, 97%
Tetrahydrothiophene 1-oxide, 97%
Tetrahydrothiophene 1-oxide, 97%
Thermo Scientific Chemicals

Tetrahydrothiophene 1-oxide, 97%

CAS: 1600-44-8 | C4H8OS | 104.167 g/mol
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10 g
50 g
Catalog number A17502.09
also known as A17502-09
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Chemical Identifiers
CAS1600-44-8
IUPAC Name1λ⁴-thiolan-1-one
Molecular FormulaC4H8OS
InChI KeyISXOBTBCNRIIQO-UHFFFAOYSA-N
SMILESO=S1CCCC1
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SpecificationsSpecification SheetSpecification Sheet
Assay (GC)≥96.0%
Refractive Index1.5190-1.5240 @ 20?C
Identification (FTIR)Conforms
Appearance (Color)Clear colorless to yellow
FormLiquid
In a comparative study of aromatic fluorodenitration with Potassium fluoride, in several dipolar aprotic solvents, a much faster reaction rate was observed with DMSO or tetramethylene sulfoxide than with the more commonly used Sulfolane.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
In a comparative study of aromatic fluorodenitration with Potassium fluoride, in several dipolar aprotic solvents, a much faster reaction rate was observed with DMSO or tetramethylene sulfoxide than with the more commonly used Sulfolane.

Solubility
Fully miscible in water.

Notes
Keep container tightly closed. Store away from oxidizing agents.
RUO – Research Use Only

General References:

  1. Philippe Renaud.; Nadira Moufid.; Lung Huang Kuo.; Dennis P. Curran. Altering the Stereochemistry of Allylation Reactions of Cyclic .alpha.-Sulfinyl Radicals: Effects of Solvents and Lewis Acids. J. Org. Chem. 1994, 59, (13), 3547-3552.
  2. Songping Wu.; Guobang Gu. Extraction of gold, palladium, and platinum from acidic media with cyclic sulfoxide derivative. Journal of University of Science and Technology Beijing, Mineral, Metallurgy, Material. 2007, 14, (2), 107-111.
  3. In a comparative study of aromatic fluorodenitration with Potassium fluoride, 14130 in several dipolar aprotic solvents, a much faster reaction rate was observed with DMSO or tetramethylene sulfoxide than with the more commonly used Sulfolane, A13466: J. Fluorine Chem., 35, 591 (1987).