Thermo Scientific Chemicals

Di-tert-butylchlorophosphine, 96%, Thermo Scientific Chemicals

Catalog number: B20998.14
25 g, Each
Thermo Scientific Chemicals

Di-tert-butylchlorophosphine, 96%, Thermo Scientific Chemicals

Catalog number: B20998.14
25 g, Each
Quantity
Catalog number: B20998.14
also known as B20998-14
Price (USD)
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Chemical Identifiers

CAS
13716-10-4
IUPAC Name
di-tert-butyl(chloro)phosphane
Molecular Formula
C8H18ClP
InChI Key
MCRSZLVSRGTMIH-UHFFFAOYSA-N
SMILES
CC(C)(C)P(Cl)C(C)(C)C
Assay (GC)
≥95.0%
Identification (FTIR)
Conforms
Appearance (Color)
Clear colorless
Refractive Index
1.4805-1.4865 @ 20?C
Form
Liquid

Description

Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.

Solubility
Miscible with terahydrofuran.

Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong reducing agents.
RUO – Research Use Only

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