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Thermo Scientific Chemicals
2-Bromopropionyl bromide, 97%
CAS: 563-76-8 | C3H4Br2O | 215.872 g/mol
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Catalog number B22504.36
also known as B22504-36
Price (EUR)
117,65
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Quantity:
500 g
Price (EUR)
117,65
Online Exclusive
131,00Save 13,35 (10%)
Each
Chemical Identifiers
CAS563-76-8
IUPAC Name2-bromopropanoyl bromide
Molecular FormulaC3H4Br2O
InChI KeyILLHORFDXDLILE-UHFFFAOYNA-N
SMILESCC(Br)C(Br)=O
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Specifications
Specification Sheet
Specification SheetAppearance (Color)Clear colorless to yellow or pink
FormLiquid
Assay (GC)≥96.0%
Identification (FTIR)Conforms
Refractive Index1.5175-1.5225 @ 20?C
2-Bromopropionyl bromide is used in the preparation of cellulose macroinitiator through direct acylation of cellulose in ionic liquid 1-allyl-3-methylimidazolium chloride. It is also used to prepare 3-(2-bromopropionyl)-2-oxazolidone derivatives and bromoester terminated poly(3-hexylthiophene). Further, it is used as a macroinitiator for atom transfer radical polymerization of acrylates.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
2-Bromopropionyl bromide is used in the preparation of cellulose macroinitiator through direct acylation of cellulose in ionic liquid 1-allyl-3-methylimidazolium chloride. It is also used to prepare 3-(2-bromopropionyl)-2-oxazolidone derivatives and bromoester terminated poly(3-hexylthiophene). Further, it is used as a macroinitiator for atom transfer radical polymerization of acrylates.
Solubility
Miscible with trichloromethane, diethyl ether, benzene and acetone.
Notes
Incompatible with water, alcohols, oxidizing agents and strong alkalis.
2-Bromopropionyl bromide is used in the preparation of cellulose macroinitiator through direct acylation of cellulose in ionic liquid 1-allyl-3-methylimidazolium chloride. It is also used to prepare 3-(2-bromopropionyl)-2-oxazolidone derivatives and bromoester terminated poly(3-hexylthiophene). Further, it is used as a macroinitiator for atom transfer radical polymerization of acrylates.
Solubility
Miscible with trichloromethane, diethyl ether, benzene and acetone.
Notes
Incompatible with water, alcohols, oxidizing agents and strong alkalis.
RUO – Research Use Only
General References:
- Xue, X.; Yang, J.; Huang, W.; Yang, H.; Jiang, B. Synthesis of Hyperbranched Poly(epsilon-caprolactone) Containing Terminal Azobenzene Structure via Combined Ring-Opening Polymerization and Click Chemistry. Polymers 2015, 7 (7), 1248-1268.
- Huang, X.; Zhang, N.; Ban, L.; Su, H. Synthesis of Star Poly(N-isopropylacrylamide) with a Core of Cucurbit[6]uril via ATRP and Controlled Thermoresponsivity. Macromol. Rapid Commun. 2015, 36 (3), 311-318.