2-Methoxypropene, 95%, stab. with ca 0.5% potassium carbonate
2-Methoxypropene, 95%, stab. with ca 0.5% potassium carbonate
2-Methoxypropene, 95%, stab. with ca 0.5% potassium carbonate
Thermo Scientific Chemicals

2-Methoxypropene, 95%, stab. with ca 0.5% potassium carbonate

CAS: 116-11-0 | C4H8O | 72.107 g/mol
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50 g
250 g
Catalog number B24083.30
also known as B24083-30
Price (USD)
161.00
Each
Quantity:
250 g
Request bulk or custom format
Price (USD)
161.00
Each
Chemical Identifiers
CAS116-11-0
IUPAC Name2-methoxyprop-1-ene
Molecular FormulaC4H8O
InChI KeyYOWQWFMSQCOSBA-UHFFFAOYSA-N
SMILESCOC(C)=C
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SpecificationsSpecification SheetSpecification Sheet
FormLiquid
Appearance (Color)Clear colorless
Assay (GC)≥94.0%
Refractive Index1.3805-1.3865 @ 20?C
Identification (FTIR)Conforms
It is used for Synthesis of heterocycle compounds and an important intermediate of medicine.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
It is used for Synthesis of heterocycle compounds and an important intermediate of medicine.

Solubility
Insoluble in water.

Notes
Light sensitive. Store in a cool, dry place in tightly closed container.
RUO – Research Use Only

General References:

  1. Erick M. Carreira; Wheeseong Lee; Robert A. Singer. Catalytic, Enantioselective Acetone Aldol Additions with 2-Methoxypropene. J. Am. Chem. Soc. 1995, 117 (12), 3649-3650.
  2. D. V. Gorlov; M. A. Kurykin; O. E. Petrova. Acylation of 2-methoxypropene with anhydrides and halides of perfluorocarboxylic acids in the presence of tertiary amines. Russian Chemical Bulletin. 1999, 48 (9), 1791-1792.
  3. Can be used, in the presence of an acid catalyst, for the introduction of the methoxyisopropyl protecting group for alcohols, readily removed under mild acid conditions. Unlike dihydropyran, the resulting acetals do not contain additional chiral centers (i.e. only a single diastereomer results): J. Am. Chem. Soc., 89, 3366 (1967); 94, 7827 (1972); 100, 4616 (1978).
  4. Diols have been protected as their acetonides in the presence of dry HBr in dichloromethane: J. Am. Chem. Soc., 100, 4620 (1978), or TsOH in DMF: J. Chem. Soc., Chem. Commun., 21 (1980), used for selective protection of a 1,3- rather than a 1,2-diol in a sugar.