Trifluorometanosulfonato de hierro (III), téc. 90 %, Thermo Scientific Chemicals

Name: Trifluorometanosulfonato de hierro (III), téc. 90 %, Thermo Scientific Chemicals
SKU: H60034.03

CAS: 63295-48-7 | C3F9FeO9S3 | 503.035 g/mol

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Cantidad:

250 mg

1 g

5 g

Número de catálogo H60034.03

también denominado H60034-03

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Cantidad:

1 g

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Identificadores químicos

CAS63295-48-7

IUPAC Nameiron(3+) tritrifluoromethanesulfonate

Molecular FormulaC3F9FeO9S3

InChI KeyOSHOQERNFGVVRH-UHFFFAOYSA-K

SMILES[Fe+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F

Especificaciones Specification Sheet

Hoja de especificaciones

Assay (Titration)>88.0%

Iron(III) triflate is used as an efficient catalyst in the synthesis of 2,3-unsaturated-O-glycosides from 2,4,6-tri-O-acetyl-D-glucal. It is also involved in the synthesis of a variety of beta-enamino ketones and esters.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Aplicaciones
El triflato de hierro (III) se utiliza como catalizador eficaz en la síntesis de O-glucósidos 2,3-insaturados de 2,4,6-tri-O-acetil-D-glucal. También participa en la síntesis de una variedad de beta-enaminocetonas y ésteres.

Solubilidad
Soluble en agua, metanol y acetonitrilo.

Nota
Sensible a la humedad. Mantener el recipiente bien cerrado en un lugar seco y bien ventilado. Incompatible con agentes oxidantes fuertes.

RUO – Research Use Only

General References:

Xolin, A.; Stevenin, A.; Pucheault, M.; Norsikian, S.; Boyer, F. D.; Beau, J. M. Glycosylation with N-acetyl glycosamine donors using catalytic iron (iii) triflate: from microwave batch chemistry to a scalable continuous-flow process. Org Chem Front 2014, 1 (8), 992-1000.
Feng, C. L.; Chu, N. N.; Zhang, S. G.; Cai, J.; Chen, J. Q.; Hu, H. Y.; Ji, M. Solvent-free synthesis of beta-enamino ketones and esters catalysed by recyclable iron (III) triflate. Chem. Pap. 2014, 68 (8), 1097-1103.