Bis[2-(diphenylphosphino)ethyl]ammonium chloride, 97+%

CAS: 66534-97-2 | C28H30ClNP2 | 477.95 g/mol

製品番号（カタログ番号）	数量
H60250.06 または、製品番号H60250-06	5 g

製品番号（カタログ番号） H60250.06

または、製品番号H60250-06

価格（JPY）

一括またはカスタム形式をリクエストする

CAS66534-97-2

化学物質名または材質Bis[2-(diphenylphosphino)ethyl]ammonium chloride

式量477.95

健康被害1H315-H319-H335

健康被害2GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

さらに表示

It is involved in the Synthesis of the new chiral aminodiphosphine ligands.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
It is involved in the Synthesis of the new chiral aminodiphosphine ligands.

Solubility
Insoluble in water.

Notes
Air Sensitive. Incompatible with oxidizing agents.

RUO – Research Use Only

General References:

Claudio Bianchini.; Erica Farnetti.; Lionel Glendenning.; Mauro Graziani.; Giorgio Nardin.; Maurizio Peruzzini.; Eliana Rocchini.; Fabrizio Zanobini. Synthesis of the New Chiral Aminodiphosphine Ligands (R)- and (S)-(.alpha.-Methylbenzyl)bis(2-(diphenylphosphino)ethyl)amine and Their Use in the Enantioselective Reduction of .alpha.,.beta.-Unsaturated Ketones to Allylic Alcohols by Iridium Catalysis. Organometallics. 1995, 14 (3),1489-1502.
Ralph G. Nuzzo.; Sharon L. Haynie.; Michael E. Wilson.; George M. Whitesides. Synthesis of functional chelating diphosphines containing the bis[2-(diphenylphosphino)ethyl]amino moiety and the use of these materials in the preparation of water-soluble diphosphine complexes of transition metals. J. Org. Chem. 1981, 46 (14),2861-2867.