Thermo Scientific Chemicals

5-Hexynenitrile, 98%, Thermo Scientific Chemicals

Catalog number: L02604.06
5 g, Each
Thermo Scientific Chemicals

5-Hexynenitrile, 98%, Thermo Scientific Chemicals

Catalog number: L02604.06
5 g, Each
Quantity
Catalog number: L02604.06
also known as L02604-06
Price (USD)
Price: 114.00
Online price: 96.65
Your price:
Quantity
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Chemical Identifiers

CAS
14918-21-9
IUPAC Name
hex-5-ynenitrile
Molecular Formula
C6H7N
InChI Key
JZYKFLLRVPPISG-UHFFFAOYSA-N
SMILES
C#CCCCC#N
Appearance (Color)
Clear, colourless to pale yellow
Form
Liquid
Identification (FTIR)
Conforms
Refractive Index
1.4385 - 1.4425 @ 20?C
Assay (GC)
≥97.5%

Description

5-Hexynenitrile is used in the preparation of annelated symmetric and asymmetric 3,3'-disubstituted 2,2'-bipyridines by cobalt(I)-catalyzed [2+2+2] cycloadditions with 1,3-diynes. Further, it reacts with 3-bromo-pyridine to prepare 6-(3-pyridinyl)-5-hexynenitrile.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
5-Hexynenitrile is used in the preparation of annelated symmetric and asymmetric 3,3′-disubstituted 2,2′-bipyridines by cobalt(I)-catalyzed [2+2+2] cycloadditions with 1,3-diynes. Further, it reacts with 3-bromo-pyridine to prepare 6-(3-pyridinyl)-5-hexynenitrile.

Solubility
Miscible with water.

Notes
Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong bases.
RUO – Research Use Only

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