3,4,6-Tri-O-acetyl-D-glucal, 98%, Thermo Scientific Chemicals
3,4,6-Tri-O-acetyl-D-glucal, 98%, Thermo Scientific Chemicals
3,4,6-Tri-O-acetyl-D-glucal, 98%, Thermo Scientific Chemicals
3,4,6-Tri-O-acetyl-D-glucal, 98%, Thermo Scientific Chemicals
Thermo Scientific Chemicals

3,4,6-Tri-O-acetyl-D-glucal, 98%, Thermo Scientific Chemicals

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Catalog NumberQuantity
L14103.14
also known as L14103-14
25 g
Catalog number L14103.14
also known as L14103-14
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78.65
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25 g
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Price (USD)/ Each
78.65
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Online exclusive
Ends: 26-Sep-2025
91.90
Save 13.25 (14%)
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Chemical Identifiers
IUPAC Name[3,4-bis(acetyloxy)-3,4-dihydro-2H-pyran-2-yl]methyl acetate
Molecular FormulaC12H16O7
InChI KeyLLPWGHLVUPBSLP-UHFFFAOYNA-N
SMILESCC(=O)OCC1OC=CC(OC(C)=O)C1OC(C)=O
Molecular Weight (g/mol)272.25
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SpecificationsSpecification SheetSpecification Sheet
FormCrystals or powder or crystalline powder
Melting Point (clear melt)51-58°C
Appearance (Color)White
Optical Rotation-24±2° (c=1 in chloroform)
Assay (GC)≥97.5%
3,4,6-Tri-O-acetyl-D-glucal acts as a building block for the synthesis of oligosaccharides in both solution and solid-phase. Further, it is used in the preparation of D-arabino-1,5-anhydro-2-deoxy-hex-1-enitol.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
3,4,6-Tri-O-acetyl-D-glucal acts as a building block for the synthesis of oligosaccharides in both solution and solid-phase. Further, it is used in the preparation of D-arabino-1,5-anhydro-2-deoxy-hex-1-enitol.

Solubility
Soluble in chloroform and ethanol. Insoluble in water.

Notes
Moisture sensitive. Store in a cool place. Incompatible with strong oxidizing agents and strong acids.
RUO – Research Use Only

General References:

  1. Chen, P.; Bi, B. Preparation of 2,3-unsaturated pseudoglycosides with Ferrier Rearrangement promoted by Tm(OTf)3 as a highly efficient catalyst. Tetrahedron Lett. 2015, 56 (34), 4895-4899.
  2. Mirabella, S.; Cardona, F.; Goti, A. Osmium-Catalyzed Tethered Aminohydroxylation of Glycals: A Stereodirected Access to 2- and 3-Aminosugars. Org. Lett. 2015, 17 (3), 728-731.