Formic acid hydrazide, 98%

Name: Formic acid hydrazide, 98%
SKU: A14901.22

CAS: 624-84-0 | CH4N2O | 60.056 g/mol

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100 g

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Catalog number A14901.22

also known as A14901-22

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100 g

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Chemical Identifiers

CAS624-84-0

IUPAC Nameformohydrazide

Molecular FormulaCH4N2O

InChI KeyXZBIXDPGRMLSTC-UHFFFAOYSA-N

SMILESNNC=O

Specifications

Specification Sheet

Appearance (Color)White to pale pink

FormCrystals or powder or crystalline powder or flakes

Assay (Hydrazine)≥97.5 to ≤102.5%

Identification (FTIR)Conforms

Melting Point (clear melt)53.0-60.0?C

Formic acid hydrazide is used as a precursor in the preparation of 1,2,4-triazole derivatives. It is also used in the synthesis of 6-N-formylamino-12,13-dihydro-1,11-dihydroxy-13-(beta-D-glucopyranosyl)-5H-indolo[2,3-a]-pyrrolo[3,4-c]carbazole-5,7(6H)-dione, which is an anticancer agent.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Formic acid hydrazide is used as a precursor in the preparation of 1,2,4-triazole derivatives. It is also used in the synthesis of 6-N-formylamino-12,13-dihydro-1,11-dihydroxy-13-(beta-D-glucopyranosyl)-5H-indolo[2,3-a]-pyrrolo[3,4-c]carbazole-5,7(6H)-dione, which is an anticancer agent.

Solubility
Soluble in water, ethanol and acetone.

Notes
Hygroscopic. Incompatible with strong oxidizing agents and strong bases.

RUO – Research Use Only

General References:

Bokor, É.; Fekete, A.; Varga, G.; Szőcs, B.; Czifrák, K.; Komáromi, I.; Somsák, L. C-(beta-D-Glucopyranosyl)formamidrazones, formic acid hydrazides and their transformations into 3-(beta-D-glucopyranosyl)-5-substituted-1,2,4-triazoles: a synthetic and computational study. Tetrahedron 2013, 69 (48), 10391-10404.
Guin, S.; Rout, S. K.; Gogoi, A.; Nandi, S.; Ghara, K. K.; Patel, B. K. Desulfurization Strategy in the Construction of Azoles Possessing Additional Nitrogen, Oxygen or Sulfur using a Copper(I) Catalyst. Adv. Synth. Catal. 2012, 354 (14-15), 2757-2770.