Eight macrocyclic bisamides and tetramides have been synthesized by reaction of dimethyl pyridine-2,6-dicarboxylate 1 with α,ω-diaminoethers in methanol as a solvent. Silver(I) coordination polymer and nine-coordinated cadmium(II) complex with dimethyl pyridine-2,6-dicarboxylate supported by solid state and electrochemical studies
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Aplicaciones
Se han sintetizado ocho bisamidas y tetramidas macrocíclicas mediante reacción de dimetilpiridina-2,6-dicarboxilato (1) con α,ω-diaminoéteres en metanol como disolvente. Polímero de coordinación de plata (I) y complejo de cadmio (II) de nueve coordinados con dimetilpiridina-2,6-dicarboxilato respaldadopor estudios electroquímicos y de estado sólido.
Solubilidad
Soluble en agua (14 g/l) (25 °C). Soluble en cloroformo.
Notas
Almacenar en un lugar fresco. Mantener el recipiente bien cerrado en un lugar seco y bien ventilado. Almacenar lejos de los agentes oxidantes fuertes.
RUO – Research Use Only
General References:
- J.-Y. Huang,l,; W. Xu. Dimethyl pyridine-2,6-dicarboxylate . Acta Cryst. 200662 2653-2654.
- Mohammad Hakimia,; Keyvan Moeinia,; Zahra Mardania,; Esther Schuhb,; Fabian Mohrb. Silver(I) coordination polymer and nine-coordinated cadmium(II) complex with dimethyl pyridine-2,6-dicarboxylate supported by solid state and electrochemical studies. Journal name. 2013, 66(7),1129-1141.