Bis(2,2,2-trifluoroethyl) phosphite was used in the synthesis of bis(2,2,2-trifluoroethyl phosphorochloridate. It was also employed as reagent for the synthesis of mono- and diesters of phosphorous acid.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Aplicaciones
Se utilizó fosfito de bis(2,2,2-trifluoroetilo) en la síntesis de fosforoclorhidrato de bis(2,2,2-trifluoroetilo). También se utilizó como reactivo para la síntesis de mono y diésteres de ácido fosforoso.
Notas
Almacenar a temperatura ambiente. Evitar los agentes oxidantes fuertes.
RUO – Research Use Only
General References:
- Guy D. Joly.; Eric N. Jacobsen. Thiourea-Catalyzed Enantioselective Hydrophosphonylation of Imines: Practical Access to Enantiomerically Enriched α-Amino Phosphonic Acids. J. Am. Chem. Soc. 2004, 126 (13),4102-4103.
- Richard J Cohen.; Daniel L Fox.; Jarrod F Eubank.; Ralph Nicholas Salvatore. Mild and efficient Cs2CO3-promoted synthesis of phosphonates. Tetrahedron Lett. 2003, 44 (47),8617-8621.