Search

  • Contáctenos
  • Orden Rápida
Búsqueda por elementosBúsqueda por elementosBúsqueda por estructuraBúsqueda por estructura
Tris[3,5-bis(trifluorometil)fenil]fosfina, 94 %, Thermo Scientific Chemicals
Tris[3,5-bis(trifluorometil)fenil]fosfina, 94 %, Thermo Scientific Chemicals
Tris[3,5-bis(trifluorometil)fenil]fosfina, 94 %, Thermo Scientific Chemicals
Thermo Scientific Chemicals

Tris[3,5-bis(trifluorometil)fenil]fosfina, 94 %, Thermo Scientific Chemicals

CAS: 175136-62-6 | C24H9F18P | 670.281 g/mol
Have Questions?
Número de catálogoCantidad
L06941.03
también denominado L06941-03
1 g
Número de catálogo L06941.03
también denominado L06941-03
Precio (USD)
-
Cantidad:
1 g
Pedido a granel o personalizado
Identificadores químicos
CAS175136-62-6
IUPAC Nametris[3,5-bis(trifluoromethyl)phenyl]phosphane
Molecular FormulaC24H9F18P
InChI KeyITJHLZVYLDBFOJ-UHFFFAOYSA-N
SMILESFC(F)(F)C1=CC(=CC(=C1)P(C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F)C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F)C(F)(F)F
Ver más
EspecificacionesSpecification SheetHoja de especificaciones
Identification (FTIR)Conforms
FormCrystals or powder or crystalline powder
Melting Point (clear melt)94.0-107.0?C
Appearance (Color)Pale cream to cream to yellow to brown
Assay (GC)≥92.0%
Tris[3,5-bis(trifluoromethyl)phenyl]phosphine is used as ligands which is useful as catalysts in various reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Aplicaciones
La tris[3,5-bis(trifluorometil)fenil]fosfina se utiliza como ligando que es útil como catalizador en diversas reacciones.

Solubilidad
Insoluble en agua.

Notas
Estable en las condiciones de almacenamiento recomendadas. Incompatible con agentes oxidantes.
RUO – Research Use Only

General References:

  1. Shin-ichiro Fujita; Shinya Fujisawa; Bhalchandra M.Bhanage; Masahiko Arai. Rhodium-tris(3,5-bis(trifluoromethyl)phenyl)phosphine catalyzed hydroformylation of dienes to dialdehydes in supercritical carbon dioxide with high activity. Tetrahedron Letters. 2004, 45,(6), 1307-1310.
  2. Tatsuo Ishiyama; Hironori Isou; Takao Kikuchi; Norio Miyaura. Ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron catalyzed by iridium-phosphine complexes. Chem. Commun. 2010, 46,(1), 159-161.
  3. In a study of coupling reactions in supercritical CO2, catalyzed by Tris(dibenzyl ideneacetone) dipalladium(0) , 12760, this ligand was among the best tried in both the Stille and Heck reactions, giving much superior results to e.g. triphenyl- or tri(o-tolyl)phosphine: Chem. Commun., 1397 (1998). See also Tri(2-furyl) phosphine, L13329, Tris(pentafluorophenyl) phosphine, L02748