Thermo Scientific Chemicals

Hexamethylphosphorous triamide, 97%, Thermo Scientific Chemicals

Catalog number: A12571.09
10 g, Each
Thermo Scientific Chemicals

Hexamethylphosphorous triamide, 97%, Thermo Scientific Chemicals

Catalog number: A12571.09
10 g, Each
Quantity
Catalog number: A12571.09
also known as A12571-09
Price (EUR)
Quantity
-

Chemical Identifiers

CAS
1608-26-0
IUPAC Name
[bis(dimethylamino)phosphanyl]dimethylamine
Molecular Formula
C6H18N3P
InChI Key
XVDBWWRIXBMVJV-UHFFFAOYSA-N
SMILES
CN(C)P(N(C)C)N(C)C
Refractive Index
1.4630-1.4680 @ 20?C
Appearance (Color)
Clear colorless to pale yellow
Form
Liquid
Assay (GC)
≥96.0%
Identification (FTIR)
Conforms

Description

Hexamethylphosphorous triamide is used as a reagent in organic synthesis as a phosphorylating agent. It is associated with carbon tetrachloride for the substitution of hydroxy groups with chlorides. It is involved in the preparation of epoxides and arene oxides from aldehydes and aryldialdehdyes respectively. It is used in the preparation of carbonates as well as reduction of ozonides.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Hexamethylphosphorous triamide is used as a reagent in organic synthesis as a phosphorylating agent. It is associated with carbon tetrachloride for the substitution of hydroxy groups with chlorides. It is involved in the preparation of epoxides and arene oxides from aldehydes and aryldialdehdyes respectively. It is used in the preparation of carbonates as well as reduction of ozonides.

Solubility
Miscible with water.

Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.
RUO – Research Use Only

Figures

Documents & Downloads

Certificates

    Frequently asked questions (FAQs)

    Citations & References

    Search citations by name, author, journal title or abstract text

    Safety and Handling


    Classification of the substance or mixture
    CLP classification - Regulation(EC) No 1272/2008
    Flammable liquids
    Category 3
    Skin Corrosion/Irritation
    Category 2
    Serious Eye Damage/Eye Irritation
    Category 2
    Carcinogenicity
    Category 2
    Specific target organ toxicity - (single exposure)
    Category 3
    Label Elements
    Signal Word

    Warning

    Hazard Statements

    H315 - Causes skin irritation

    H319 - Causes serious eye irritation

    H335 - May cause respiratory irritation

    H351 - Suspected of causing cancer

    Physical Hazards

    H226 - Flammable liquid and vapor

    Precautionary Statements

    P261 - Avoid breathing dust/fume/gas/mist/vapors/spray

    P280 - Wear protective gloves/protective clothing/eye protection/face protection

    P302 + P352 - IF ON SKIN: Wash with plenty of soap and water

    P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

    P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking