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Trifluoroacetaldehyde hydrate, tech., ca 75% in water, Thermo Scientific Chemicals
Catalog number: A13234.09
10 g, Each
Thermo Scientific Chemicals
Trifluoroacetaldehyde hydrate, tech., ca 75% in water, Thermo Scientific Chemicals
Catalog number: A13234.09
10 g, Each
Quantity
Catalog number: A13234.09
also known as A13234-09
Price (EUR)
74,79 Online price
83,10
Each
Quantity
-
Chemical Identifiers
CAS
421-53-4
IUPAC Name
2,2,2-trifluoroacetaldehyde
Molecular Formula
C2HF3O
InChI Key
JVTSHOJDBRTPHD-UHFFFAOYSA-N
SMILES
FC(F)(F)C=O
Specifications
Specification SheetAssay (Aqueous acid-base Titration)
70 - 80%
Refractive Index
1.3375 - 1.3415 @20?C
Form
liquid
Comment
Hydrate reacts with KF reagent as well as free water
Water Content (Karl Fischer Titration)
ca. 41 - 32%
Description
One general application of trifluoroacetaldehyde is the preparation of trifluoroethylamino derivatives via reductive amination reaction. This synthesis includes the formation of the corresponding N,O-acetal intermediates followed by their reduction using NaBH4 or 2-picoline borane complex, affording the target trifluoroethylamino compounds in moderate to good yields. Another general application of trifluoroacetaldehyde is the synthesis of chiral α-substituted trifluoroethylamino compounds.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
One general application of trifluoroacetaldehyde is the preparation of trifluoroethylamino derivatives via reductive amination reaction. This synthesis includes the formation of the corresponding N,O-acetal intermediates followed by their reduction using NaBH4 or 2-picoline borane complex, affording the target trifluoroethylamino compounds in moderate to good yields. Another general application of trifluoroacetaldehyde is the synthesis of chiral α-substituted trifluoroethylamino compounds.
Solubility
Soluble in water.
Notes
Store at room temperature. Incompatible with oxidizing agents. Keep in cool place.
One general application of trifluoroacetaldehyde is the preparation of trifluoroethylamino derivatives via reductive amination reaction. This synthesis includes the formation of the corresponding N,O-acetal intermediates followed by their reduction using NaBH4 or 2-picoline borane complex, affording the target trifluoroethylamino compounds in moderate to good yields. Another general application of trifluoroacetaldehyde is the synthesis of chiral α-substituted trifluoroethylamino compounds.
Solubility
Soluble in water.
Notes
Store at room temperature. Incompatible with oxidizing agents. Keep in cool place.
RUO – Research Use Only
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Safety and Handling
Classification of the substance or mixture
CLP classification - Regulation(EC) No 1272/2008
Flammable liquids
Category 2
Acute oral toxicity
Category 4
Skin Corrosion/Irritation
Category 2
Serious Eye Damage/Eye Irritation
Category 1
Skin Sensitization
Category 1
Specific target organ toxicity - (single exposure)
Category 3
Label Elements
Signal Word
Danger
Hazard Statements
H302 - Harmful if swallowed
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H318 - Causes serious eye damage
H335 - May cause respiratory irritation
Physical Hazards
H225 - Highly flammable liquid and vapor
Precautionary Statements
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower
P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician