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Triethyl phosphonoacetate, 98+%, Thermo Scientific Chemicals
Catalog number: A14120.36
500 g, Each
Thermo Scientific Chemicals
Triethyl phosphonoacetate, 98+%, Thermo Scientific Chemicals
Catalog number: A14120.36
500 g, Each
Quantity
Catalog number: A14120.36
also known as A14120-36
Price (EUR)
200,70 Online price
223,00
Each
Quantity
-
Chemical Identifiers
CAS
867-13-0
IUPAC Name
ethyl 2-(diethoxyphosphoryl)acetate
Molecular Formula
C8H17O5P
InChI Key
GGUBFICZYGKNTD-UHFFFAOYSA-N
SMILES
CCOC(=O)CP(=O)(OCC)OCC
Specifications
Specification SheetAssay (GC)
≥98.0%
Refractive Index
1.4300-1.4340 @ 20?C
Appearance (Color)
Clear colorless
Identification (FTIR)
Conforms
Form
Liquid
Description
Triethyl phosphonoacetate serves as a reactant used in Horner-Wadsworth-Emmons reactions, Tsuji-Trost type reactions, Intramolecular Heck-type cyclization and isomerizations and Intramolecular aryne-ene reactions. In Horner-Wadsworth-Emmons reaction, it is utilized as a reagent to prepare chiral 2-methylcyclopropanecarboxylic acid from (S)-propylene oxide.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Triethyl phosphonoacetate serves as a reactant used in Horner-Wadsworth-Emmons reactions, Tsuji-Trost type reactions, Intramolecular Heck-type cyclization and isomerizations and Intramolecular aryne-ene reactions. In Horner-Wadsworth-Emmons reaction, it is utilized as a reagent to prepare chiral 2-methylcyclopropanecarboxylic acid from (S)-propylene oxide.
Solubility
Slightly miscible with water.
Notes
Incompatible with strong oxidizing agents.
Triethyl phosphonoacetate serves as a reactant used in Horner-Wadsworth-Emmons reactions, Tsuji-Trost type reactions, Intramolecular Heck-type cyclization and isomerizations and Intramolecular aryne-ene reactions. In Horner-Wadsworth-Emmons reaction, it is utilized as a reagent to prepare chiral 2-methylcyclopropanecarboxylic acid from (S)-propylene oxide.
Solubility
Slightly miscible with water.
Notes
Incompatible with strong oxidizing agents.
RUO – Research Use Only
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Safety and Handling
Classification of the substance or mixture
CLP classification - Regulation(EC) No 1272/2008
Skin Corrosion/Irritation
Category 2
Serious Eye Damage/Eye Irritation
Category 1
Specific target organ toxicity - (single exposure)
Category 3
Label Elements
Signal Word
Danger
Hazard Statements
H315 - Causes skin irritation
H318 - Causes serious eye damage
H335 - May cause respiratory irritation
Precautionary Statements
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P280 - Wear eye protection/ face protection
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician