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2-Bromo-6-methoxynaphthalene, 98%
2-Bromo-6-methoxynaphthalene, 98%
2-Bromo-6-methoxynaphthalene, 98%
Thermo Scientific Chemicals

2-Bromo-6-methoxynaphthalene, 98%

CAS: 5111-65-9 | C11H9BrO | 237.096 g/mol
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Catalog number A19450.18
also known as A19450-18
Price (EUR)
159,00
Each
Quantity:
50 g
Request bulk or custom format
Price (EUR)
159,00
Each
Chemical Identifiers
CAS5111-65-9
IUPAC Name2-bromo-6-methoxynaphthalene
Molecular FormulaC11H9BrO
InChI KeyAYFJBMBVXWNYLT-UHFFFAOYSA-N
SMILESCOC1=CC=C2C=C(Br)C=CC2=C1
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SpecificationsSpecification SheetSpecification Sheet
Appearance (Color)White to cream or pale pink
Melting Point (clear melt)104.0-110.0?C
FormPowder
Assay (GC)≥97.5%
2-Bromo-6-methoxynaphthalene is used in the synthesis of nabumetone [4-(6-methoxy-2-naphthalenyl)-2-butanone] by Heck reaction.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
2-Bromo-6-methoxynaphthalene is used in the synthesis of nabumetone [4-(6-methoxy-2-naphthalenyl)-2-butanone] by Heck reaction.

Solubility
Soluble in DMSO. Insoluble in water.

Notes
Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.
RUO – Research Use Only

General References:

  1. Howard Alper.; Nathalie Hamel. Asymmetric synthesis of acids by the palladium-catalyzed hydrocarboxylation of olefins in the presence of (R)-(-)- or (S)-(+)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate. J. Am. Chem. Soc. 1990, 112, (7), 2803-2804.
  2. Stephen W. Wright.; David L. Hageman.; Lester D. McClure. Fluoride-Mediated Boronic Acid Coupling Reactions. J. Org. Chem. 1994, 59, (20), 6095-6097.
  3. Undergoes highly efficient, phosphine-free Suzuki coupling reactions with arylboronic acids in water, catalyzed by Pd(II) acetate in the presence of TBAB and potassium carbonate: J. Org. Chem., 62, 7170 (1997).