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tert-Butyldichlorophosphine, 98%, Thermo Scientific Chemicals
Catalog number: H27360.18
50 g, Each
Thermo Scientific Chemicals
tert-Butyldichlorophosphine, 98%, Thermo Scientific Chemicals
Catalog number: H27360.18
50 g, Each
Quantity
Catalog number: H27360.18
also known as H27360-18
Price (EUR)
520,00
Each
Quantity
-
Chemical Identifiers
CAS
25979-07-1
IUPAC Name
tert-butyldichlorophosphane
Molecular Formula
C4H9Cl2P
InChI Key
NMJASRUOIRRDSX-UHFFFAOYSA-N
SMILES
CC(C)(C)P(Cl)Cl
Specifications
Specification SheetAppearance (Color)
White
Form
Crystalline or Fused solid
Proton NMR
Conforms to structure
Phosphorus-31 NMR
Conforms to structure
Assay (GC)
>97.5%
Description
Reactant for the synthesis of alkali metal complexes. As intermediates. tert-Butyldichlorophosphine (TBDCP) is used primarily in the preparation of monoand bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Reactant for the synthesis of alkali metal complexes. As intermediates. tert-Butyldichlorophosphine (TBDCP) is used primarily in the preparation of monoand bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.
Solubility
Reacts with water. Soluble in n-Pentane, n-Hexane, Ether, Toluene,THF. tert-Butyldichlorophosphine is infinitely soluble in hydrocarbon and ethereal solvents.
Notes
Air & Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, strong bases, air, water and moisture.
Reactant for the synthesis of alkali metal complexes. As intermediates. tert-Butyldichlorophosphine (TBDCP) is used primarily in the preparation of monoand bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.
Solubility
Reacts with water. Soluble in n-Pentane, n-Hexane, Ether, Toluene,THF. tert-Butyldichlorophosphine is infinitely soluble in hydrocarbon and ethereal solvents.
Notes
Air & Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, strong bases, air, water and moisture.
RUO – Research Use Only
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Safety and Handling
Classification of the substance or mixture
CLP classification - Regulation(EC) No 1272/2008
Skin Corrosion/Irritation
Category 1
Serious Eye Damage/Eye Irritation
Category 1
Label Elements
Signal Word
Danger
Hazard Statements
H314 - Causes severe skin burns and eye damage
EU Specific Hazard Statements
EUH014 - Reacts violently with water
EUH029 - Contact with water liberates toxic gas
Precautionary Statements
P402 + P404 - Store in a dry place. Store in a closed container
P280 - Wear eye protection/ face protection
P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician