Diethyl 1,4-dihydro-2,6-dimethylpyridine-3,5-dicarboxylate, 98%

Name: Diethyl 1,4-dihydro-2,6-dimethylpyridine-3,5-dicarboxylate, 98%
SKU: H55752.03
Price: 83.60 EUR

CAS: 1149-23-1 | C13H19NO4 | 253.298 g/mol

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Catalog number H55752.03

also known as H55752-03

Price (EUR)

83,60

Each

Quantity:

1 g

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Price (EUR)

83,60

Each

Chemical Identifiers

CAS1149-23-1

IUPAC Name3,5-diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate

Molecular FormulaC13H19NO4

InChI KeyLJXTYJXBORAIHX-UHFFFAOYSA-N

SMILESCCOC(=O)C1=C(C)NC(C)=C(C1)C(=O)OCC

Specifications

Specification Sheet

FormCrystals or powder or crystalline powder

Assay from Suppliers CofA≥97.5% to ≤102.5% (Titration)

Appearance (Color)Pale yellow to yellow to green

Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate is a hydrogen source in conjugate reduction and organocatalytic reductive amination. It is used as a hydrogen source in organocatalytic reductive amination and conjugate reduction.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate is a hydrogen source in conjugate reduction and organocatalytic reductive amination. It is used as a hydrogen source in organocatalytic reductive amination and conjugate reduction.

Solubility
Soluble in organic solvents.

Notes
Desiccate at 4°C. Keep away from oxidizing agents.

RUO – Research Use Only

General References:

Hong Sheng Li.; Yi Qun Li. Potassium iodide catalyzed reductive dehalogenation of α-halo-ketones using Hantzsch ester diethyl 1,4-dihydro-2,6-dimethylpyridine-3,5-dicarboxylate as reductant.Chin. Chem. Lett. 2010, 21 (8), 931-934.
E. A. Braude, (the late).; J. Hannah.; Reginald Linstead, Sir. 653. Hydrogen transfer. Part XVII. Homogeneous hydrogen transfer reactions from dihydrides of nitrogenous heterocycles to miscellaneous acceptors.J. Chem. Soc. 1960, (0),3257-3267.