Thermo Scientific Chemicals

Diisopropyl azodicarboxylate, 94%, Thermo Scientific Chemicals

Catalog number: L10386.14
25 g, Each
Thermo Scientific Chemicals

Diisopropyl azodicarboxylate, 94%, Thermo Scientific Chemicals

Catalog number: L10386.14
25 g, Each
Quantity
Informational:Informational:This chemical may require us to obtain additional information for our regulatory and chemical compliance records. If required, we will contact you for this information once your order is placed.
Catalog number: L10386.14
also known as L10386-14
Price (EUR)
Quantity
-

Chemical Identifiers

CAS
2446-83-5
IUPAC Name
N-{[(propan-2-yloxy)carbonyl]imino}(propan-2-yloxy)formamide
Molecular Formula
C8H14N2O4
InChI Key
VVWRJUBEIPHGQF-UHFFFAOYSA-N
SMILES
CC(C)OC(=O)N=NC(=O)OC(C)C
Appearance (Color)
Clear, orange to reddish brown
Form
Liquid
Assay (GC)
≥ 92.0%

Description

Diisopropyl azodicarboxylate is used as an important reagent in the production of many organic compounds. It is used in association with triphenyl phosphine in Mitsunobu reaction of alcohols, acids and amides. It acts as reactant in the preparation of chromenes resembling classical cannabinoids, norbornene-based guanidine-rich polymers and acceptor-donor-acceptor organic dyes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Diisopropyl azodicarboxylate is used as an important reagent in the production of many organic compounds. It is used in association with triphenyl phosphine in Mitsunobu reaction of alcohols, acids and amides. It acts as reactant in the preparation of chromenes resembling classical cannabinoids, norbornene-based guanidine-rich polymers and acceptor-donor-acceptor organic dyes.

Solubility
Immiscible with water.

Notes
Store in cool place. Light sensitive. Incompatible with strong oxidizing agents, strong bases, alcohols and metallic salts. Decomposes violently at or above: 100 0C.
RUO – Research Use Only

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    Safety and Handling


    Classification of the substance or mixture
    CLP classification - Regulation(EC) No 1272/2008
    Skin Corrosion/Irritation
    Category 2
    Serious Eye Damage/Eye Irritation
    Category 2
    Specific target organ toxicity - (single exposure)
    Category 3
    Specific target organ toxicity - (repeated exposure)
    Category 2
    Chronic aquatic toxicity
    Category 2
    Label Elements
    Signal Word

    Warning

    Hazard Statements

    H315 - Causes skin irritation

    H319 - Causes serious eye irritation

    H335 - May cause respiratory irritation

    H373 - May cause damage to organs through prolonged or repeated exposure

    H411 - Toxic to aquatic life with long lasting effects

    Precautionary Statements

    P280 - Wear protective gloves/protective clothing/eye protection/face protection

    P302 + P352 - IF ON SKIN: Wash with plenty of soap and water

    P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing

    P312 - Call a POISON CENTER or doctor if you feel unwell

    P332 + P313 - If skin irritation occurs: Get medical advice/attention

    P337 + P313 - If eye irritation persists: Get medical advice/attention