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N-Phenylbis(trifluoromethanesulfonimide), 99%, Thermo Scientific Chemicals
Catalog number: L12531.14
25 g, Each
Thermo Scientific Chemicals
N-Phenylbis(trifluoromethanesulfonimide), 99%, Thermo Scientific Chemicals
Catalog number: L12531.14
25 g, Each
Quantity
Catalog number: L12531.14
also known as L12531-14
Price (EUR)
239,40 Online price
266,00
Each
Quantity
-
Chemical Identifiers
CAS
37595-74-7
IUPAC Name
1,1,1-trifluoro-N-phenyl-N-trifluoromethanesulfonylmethanesulfonamide
Molecular Formula
C8H5F6NO4S2
InChI Key
DIOHEXPTUTVCNX-UHFFFAOYSA-N
SMILES
FC(F)(F)S(=O)(=O)N(C1=CC=CC=C1)S(=O)(=O)C(F)(F)F
Specifications
Specification SheetAppearance (Color)
White to pale cream
Assay (GC)
>98.5%
Form
crystalline solid
Clarity
2.5% w/v sol. in ethanol will be clear to very faintly turbid by JIS K8001 5.2
Description
N-Phenylbis(trifluoromethanesulfonimide) acts as a mild triflating reagent as well as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes. It is also employed as a reactant for the preparation of amphoteric alfa-boryl aldehydes. It plays an important role in the enantioselective synthesis of the core ring skeleton of leucosceptroids A-D and in steroselective sulfoxidation. Further, it is used in the enantioselective synthesis of beta-amino acids through the Mannich reaction. In addition to this, it is used in the preparation of sphingosine 1-phosphate-1 receptor agonists.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
N-Phenylbis(trifluoromethanesulfonimide) acts as a mild triflating reagent as well as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes. It is also employed as a reactant for the preparation of amphoteric alfa-boryl aldehydes. It plays an important role in the enantioselective synthesis of the core ring skeleton of leucosceptroids A-D and in steroselective sulfoxidation. Further, it is used in the enantioselective synthesis of beta-amino acids through the Mannich reaction. In addition to this, it is used in the preparation of sphingosine 1-phosphate-1 receptor agonists.
Solubility
Soluble in methanol. Slightly soluble in chloroform and ethyl acetate.
Notes
Hygroscopic. Store in a cool place. Moisture sensitive. Incompatible with strong oxidizing agents.
N-Phenylbis(trifluoromethanesulfonimide) acts as a mild triflating reagent as well as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes. It is also employed as a reactant for the preparation of amphoteric alfa-boryl aldehydes. It plays an important role in the enantioselective synthesis of the core ring skeleton of leucosceptroids A-D and in steroselective sulfoxidation. Further, it is used in the enantioselective synthesis of beta-amino acids through the Mannich reaction. In addition to this, it is used in the preparation of sphingosine 1-phosphate-1 receptor agonists.
Solubility
Soluble in methanol. Slightly soluble in chloroform and ethyl acetate.
Notes
Hygroscopic. Store in a cool place. Moisture sensitive. Incompatible with strong oxidizing agents.
RUO – Research Use Only
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Safety and Handling
Classification of the substance or mixture
CLP classification - Regulation(EC) No 1272/2008
Skin Corrosion/Irritation
Category 2
Serious Eye Damage/Eye Irritation
Category 2
Specific target organ toxicity - (single exposure)
Category 3
Label Elements
Signal Word
Warning
Hazard Statements
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H335 - May cause respiratory irritation
Precautionary Statements
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing