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Triethylborane, 1M soln. in THF, Thermo Scientific Chemicals
Catalog number: L15109.AE
100 mL, Each
Thermo Scientific Chemicals
Triethylborane, 1M soln. in THF, Thermo Scientific Chemicals
Catalog number: L15109.AE
100 mL, Each
Quantity
Catalog number: L15109.AE
also known as L15109-AE
Price (EUR)
72,99 Online price
81,10
Each
Quantity
-
Chemical Identifiers
CAS
97-94-9
IUPAC Name
triethylborane
Molecular Formula
C6H15B
InChI Key
LALRXNPLTWZJIJ-UHFFFAOYSA-N
SMILES
CCB(CC)CC
Specifications
Specification SheetForm
Liquid
Assay from Supplier's CofA
0.95-1.30 M
Appearance (Color)
Clear colorless to yellow to orange
Description
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Triethylborane is catalyst for allylation of aldehydes, decarboxylative C-C bond cleavage reactions, rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations, Regioselective hydroxyalkylation of unsaturated oxime ethers. Reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes and synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential.
Solubility
Reacts with water.
Notes
Air Sensitive, store away form air. Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.
Triethylborane is catalyst for allylation of aldehydes, decarboxylative C-C bond cleavage reactions, rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations, Regioselective hydroxyalkylation of unsaturated oxime ethers. Reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes and synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential.
Solubility
Reacts with water.
Notes
Air Sensitive, store away form air. Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.
RUO – Research Use Only
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Safety and Handling
Classification of the substance or mixture
CLP classification - Regulation(EC) No 1272/2008
Flammable liquids
Category 2
Acute oral toxicity
Category 4
Acute Inhalation Toxicity - Vapors
Category 4
Skin Corrosion/Irritation
Category 1
Serious Eye Damage/Eye Irritation
Category 1
Carcinogenicity
Category 2
Specific target organ toxicity - (single exposure)
Category 3
Label Elements
Signal Word
Danger
Hazard Statements
H302 + H332 - Harmful if swallowed or if inhaled
H314 - Causes severe skin burns and eye damage
H335 - May cause respiratory irritation
H336 - May cause drowsiness or dizziness
H351 - Suspected of causing cancer
Physical Hazards
H225 - Highly flammable liquid and vapor
EU Specific Hazard Statements
EUH014 - Reacts violently with water
EUH019 - May form explosive peroxides
Precautionary Statements
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P301 + P330 + P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician