Thermo Scientific Chemicals

Diphenyl disulfide, 98%, Thermo Scientific Chemicals

Catalog number: A12586.18
50 g, Each
Thermo Scientific Chemicals

Diphenyl disulfide, 98%, Thermo Scientific Chemicals

Catalog number: A12586.18
50 g, Each
Quantity
Catalog number: A12586.18
also known as A12586-18
Price (EUR)
Quantity
-

Chemical Identifiers

CAS
882-33-7
IUPAC Name
(phenyldisulfanyl)benzene
Molecular Formula
C12H10S2
InChI Key
GUUVPOWQJOLRAS-UHFFFAOYSA-N
SMILES
S(SC1=CC=CC=C1)C1=CC=CC=C1
Appearance (Color)
White to cream
Form
Crystals or powder or crystalline powder or fused solid
Assay (GC)
≥97.5%
Melting Point (clear melt)
57.0-63.0?C

Description

Diphenyl disulfide is one of the most popular organic disulfides used in organic synthesis. It is used as a reagent for the α-phenylsulfenylation of carbonyl compounds. It participates in hydrothiolation of alkynes via amine-mediated single electron transfer mechanism. It is the hydrolysis product of dyfonate.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Diphenyl disulfide is one of the most popular organic disulfides used in organic synthesis. It is used as a reagent for the α-phenylsulfenylation of carbonyl compounds. It participates in hydrothiolation of alkynes via amine-mediated single electron transfer mechanism. It is the hydrolysis product of dyfonate.

Solubility
Insoluble in water.

Notes
Stable under recommended storage conditions. Incompatible with oxidizing agents.
RUO – Research Use Only

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    Safety and Handling


    Classification of the substance or mixture
    CLP classification - Regulation(EC) No 1272/2008
    Skin Corrosion/Irritation
    Category 2
    Serious Eye Damage/Eye Irritation
    Category 2
    Specific target organ toxicity - (single exposure)
    Category 3
    Acute aquatic toxicity
    Category 1
    Chronic aquatic toxicity
    Category 1
    Label Elements
    Signal Word

    Warning

    Hazard Statements

    H315 - Causes skin irritation

    H319 - Causes serious eye irritation

    H335 - May cause respiratory irritation

    H410 - Very toxic to aquatic life with long lasting effects

    Precautionary Statements

    P261 - Avoid breathing dust/fume/gas/mist/vapors/spray

    P280 - Wear protective gloves/protective clothing/eye protection/face protection

    P302 + P352 - IF ON SKIN: Wash with plenty of soap and water

    P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing

    P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

    P312 - Call a POISON CENTER or doctor if you feel unwell