Methyl 5-bromonicotinate, 97%, Thermo Scientific Chemicals
Methyl 5-bromonicotinate, 97%, Thermo Scientific Chemicals
Methyl 5-bromonicotinate, 97%, Thermo Scientific Chemicals
Thermo Scientific Chemicals

Methyl 5-bromonicotinate, 97%, Thermo Scientific Chemicals

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Catalog NumberQuantity
B20908.06
also known as B20908-06
5 g
Catalog number B20908.06
also known as B20908-06
Price (EUR)
55,50
Each
Quantity:
5 g
Request bulk or custom format
Price (EUR)
55,50
Each
Chemical Identifiers
CAS29681-44-5
IUPAC Namemethyl 5-bromopyridine-3-carboxylate
Molecular FormulaC7H6BrNO2
InChI KeyAAJZXPWBILCHAW-UHFFFAOYSA-N
SMILESCOC(=O)C1=CN=CC(Br)=C1
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SpecificationsSpecification SheetSpecification Sheet
Assay (GC)≥96.0%
Melting Point (clear melt)93.5-102.5?C
Appearance (Color)White
FormPowder
A substrate used in a microwave-assisted, palladium-catalyzed arylation of acetone as its TMS enol ether.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
A substrate used in a microwave-assisted, palladium-catalyzed arylation of acetone as its TMS enol ether.

Solubility
Slightly soluble in water.

Notes
Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
RUO – Research Use Only

General References:

  1. Wayne J. Thompson, et al. A general synthesis of 5-arylnicotinates.J. Org. Chem.,1984,49(26), 5237-5243.
  2. Masahiko Iyoda, et al. Homocoupling of Aryl Halides Using Nickel(II) Complex and Zinc in the Presence of Et4NI. An Efficient Method for the Synthesis of Biaryls and Bipyridines.Bull. Chem. Soc. Jpn.,1990,63(1), 80-87.