Thermo Scientific Chemicals

(+/-)-Benzyloxycarbonyl-alpha-phosphonoglycine trimethyl ester, 97%, Thermo Scientific Chemicals

Catalog number: B22506.06
5 g, Each
Thermo Scientific Chemicals

(+/-)-Benzyloxycarbonyl-alpha-phosphonoglycine trimethyl ester, 97%, Thermo Scientific Chemicals

Catalog number: B22506.06
5 g, Each
Quantity
Catalog number: B22506.06
also known as B22506-06
Price (EUR)
Quantity
-

Chemical Identifiers

CAS
88568-95-0
IUPAC Name
methyl (2S)-2-{[(benzyloxy)carbonyl]amino}-2-(dimethoxyphosphoryl)acetate
Molecular Formula
C13H18NO7P
InChI Key
GSYSFVSGPABNNL-NSHDSACASA-N
SMILES
COC(=O)[C@@H](NC(=O)OCC1=CC=CC=C1)P(=O)(OC)OC
Assay (unspecified)
(by Carbon EA) : >96.0 to<104.0%
Elemental Analysis
(Carbon) : 45.25-49.01% (Theory 47.14%)
Elemental Analysis
(Hydrogen) : 5.25-5.69% (Theory 5.48%)
Proton NMR
Conforms to structure
Phosphorus-31 NMR
Conforms to structure

Description

(±)-Z-α-Phosphonoglycine trimethyl ester is the starting material for the synthesis of (Z)-dehydroamino acids by Wittig-Horner reaction with aldehydes, the dehydroamino acids can be stereo selectively reduced to amino acids.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(±)-Z-α-Phosphonoglycine trimethyl ester is the starting material for the synthesis of (Z)-dehydroamino acids by Wittig-Horner reaction with aldehydes, the dehydroamino acids can be stereo selectively reduced to amino acids.

Solubility
Soluble in methanol.

Notes
Store in cool, dry place in tightly closed containers. Store away from strong oxidizing agents.
RUO – Research Use Only

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    Safety and Handling


    Classification of the substance or mixture
    CLP classification - Regulation(EC) No 1272/2008
    Skin Corrosion/Irritation
    Category 2
    Serious Eye Damage/Eye Irritation
    Category 2
    Specific target organ toxicity - (single exposure)
    Category 3
    Label Elements
    Signal Word

    Warning

    Hazard Statements

    H315 - Causes skin irritation

    H319 - Causes serious eye irritation

    H335 - May cause respiratory irritation

    Precautionary Statements

    P261 - Avoid breathing dust/fume/gas/mist/vapors/spray

    P280 - Wear protective gloves/protective clothing/eye protection/face protection

    P302 + P352 - IF ON SKIN: Wash with plenty of soap and water

    P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing