Thermo Scientific Chemicals

Manganese(IV) oxide activated, tech. 90%, Thermo Scientific Chemicals

Catalog number: L13253.22
100 g, Each
Thermo Scientific Chemicals

Manganese(IV) oxide activated, tech. 90%, Thermo Scientific Chemicals

Catalog number: L13253.22
100 g, Each
Quantity
Catalog number: L13253.22
also known as L13253-22
Price (EUR)
Quantity
-

Chemical Identifiers

CAS
1313-13-9
IUPAC Name
dioxomanganese
Molecular Formula
MnO2
InChI Key
NUJOXMJBOLGQSY-UHFFFAOYSA-N
SMILES
O=[Mn]=O
Appearance (Color)
Black
Assay from Suppliers CofA
≥88.0% (≥55.6% Mn)
Form
Powder

Description

Manganese(IV) oxide is suitable for use in batteries. It is widely used for the selective oxidation of allylic and benzylic alcohols to aldehydes or ketones, as a co-oxidant in combination with 1,4-benzoquinone and in the allylic oxidation of olefins catalyzed by Palladium(II)­ acetate. It acts a reagent for oxidations. It is the source of manganese and all its compounds, largely used in manufacturing of manganese steel, for making amethyst glass, decolorizing glass, painting on porcelain, faience and majolica. The precipitate is used in electrotechnics, pigments, browning gun barrels, drier for paints and varnishes, printing and dyeing textiles.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Manganese(IV) oxide is suitable for use in batteries. It is widely used for the selective oxidation of allylic and benzylic alcohols to aldehydes or ketones, as a co-oxidant in combination with 1,4-benzoquinone and in the allylic oxidation of olefins catalyzed by Palladium(II)­ acetate. It acts a reagent for oxidations. It is the source of manganese and all its compounds, largely used in manufacturing of manganese steel, for making amethyst glass, decolorizing glass, painting on porcelain, faience and majolica. The precipitate is used in electrotechnics, pigments, browning gun barrels, drier for paints and varnishes, printing and dyeing textiles.

Solubility
Insoluble in water.

Notes
Store at room temperature. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.
RUO – Research Use Only

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    Safety and Handling


    Classification of the substance or mixture
    CLP classification - Regulation(EC) No 1272/2008
    Acute oral toxicity
    Category 4
    Acute Inhalation Toxicity - Dusts and Mists
    Category 4
    Specific target organ toxicity - (repeated exposure)
    Category 2
    Label Elements
    Signal Word

    Warning

    Hazard Statements

    H302 + H332 - Harmful if swallowed or if inhaled

    H373 - May cause damage to organs through prolonged or repeated exposure if inhaled

    Precautionary Statements

    P260 - Do not breathe dust/fume/gas/mist/vapors/spray

    P264 - Wash face, hands and any exposed skin thoroughly after handling

    P270 - Do not eat, drink or smoke when using this product

    P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing

    P312 - Call a POISON CENTER or doctor if you feel unwell