Ácido malónico, 99 %, Thermo Scientific Chemicals
Ácido malónico, 99 %, Thermo Scientific Chemicals
Ácido malónico, 99 %, Thermo Scientific Chemicals
Thermo Scientific Chemicals

Ácido malónico, 99 %, Thermo Scientific Chemicals

CAS: 141-82-2 | C3H4O4 | 104.061 g/mol
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Cantidad:
100 g
500 g
2500 g
Número de catálogo A11526.36
también denominado A11526-36
Precio (EUR)
110,00
Each
Cantidad:
500 g
Pedido a granel o personalizado
Precio (EUR)
110,00
Each
Identificadores químicos
CAS141-82-2
IUPAC Namepropanedioic acid
Molecular FormulaC3H4O4
InChI KeyOFOBLEOULBTSOW-UHFFFAOYSA-N
SMILESOC(=O)CC(O)=O
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EspecificacionesSpecification SheetHoja de especificaciones
FormCrystals or powder or crystalline powder or granules
Assay (Aqueous acid-base Titration)≥98.5 to ≤101.5% (non-U.S. sourced material)
Assay from Supplier's CofA≥98.5% (U.S. sourced material)
CommentMaterial Sourced in the U.S. and in other countries
Identification (FTIR)Conforms (non-U.S. sourced material)
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Malonic acid is acts as a building block in organic synthesis. It is also useful as a precursor for polyesters and alkyd resins, which is used in coating applications, thereby protecting against UV light, corrosion and oxidation. It acts as a cross linker in the coating industry and surgical adhesive. It finds application in the production of specialty chemicals, flavors and fragrances, polymer cross linkers and pharmaceuticals.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Aplicaciones
El ácido malónico se utiliza como compuesto básico en la síntesis orgánica. También es útil como precursor para poliésteres y resinas alquídicas, que se utiliza en aplicaciones de revestimiento, lo que protege contra la luz UV, la corrosión y la oxidación. Actúa como entrecruzador en la industria de los revestimientos y en los adhesivos quirúrgicos. Se aplica en la producción de productos químicos especiales, sabores y fragancias, entrecruzadores de polímeros y productos farmacéuticos.

Solubilidad
Soluble en agua fría.

Notas
Incompatible con bases, agentes oxidantes y agentes reductores.
RUO – Research Use Only

General References:

  1. Knoevenagel condensation with aldehydes yields substituted acrylic (e.g. cinnamic) acids; review: Org. React., 15, 204 (1967). For an example of the Doebner modification, using pyridine as solvent/base, see: Org. Synth. Coll., 3, 425 (1955); a catalytic amount of piperidine often gives superior results; see, e.g.: Org. Synth. Coll., 4, 327 (1963).
  2. Bew, S. P.; Stephenson, R.; Rouden, J.; Ashford, P. A.; Bourane, M.; Charvet, A.; Dalstein, V. M. D.; Jauseau, R.; Gipson, G. D. H.; Lozano, L. A. M. Bioinspired, Base- and Metal-Free, Mild Decarboxylative Aldol Activation of Malonic Acid Half Thioesters Under Phase-Transfer Reaction Conditions. Adv. Synth. Catal. 2015, 357 (6), 1245-1257.
  3. Nakamura, S.; Sano, M.; Toda, A.; Nakane, D.; Masuda, H. Organocatalytic Enantioselective Decarboxylative Reaction of Malonic Acid Half Thioesters with Cyclic N-Sulfonyl Ketimines by Using N-Heteroarenesulfonyl Cinchona Alkaloid Amides. Chem. Eur. J. 2015, 21 (10), 3929-3932.