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1-Fluoro-4-yodobenceno, 99 %, Thermo Scientific Chemicals
1-Fluoro-4-yodobenceno, 99 %, Thermo Scientific Chemicals
1-Fluoro-4-yodobenceno, 99 %, Thermo Scientific Chemicals
Thermo Scientific Chemicals

1-Fluoro-4-yodobenceno, 99 %, Thermo Scientific Chemicals

CAS: 352-34-1 | C6H4FI | 222.00 g/mol
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Cantidad:
10 g
50 g
250 g
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Número de catálogo A12008.18
también denominado A12008-18
Precio (EUR)
97,20
Each
Cantidad:
50 g
Pedido a granel o personalizado
Precio (EUR)
97,20
Each
Identificadores químicos
CAS352-34-1
EspecificacionesSpecification SheetHoja de especificaciones
Appearance (Color)Clear colorless to yellow
FormLiquid
Assay (GC)≥98.5%
Identification (FTIR)Conforms
Refractive Index1.5815-1.5845 @ 20?C
4-Fluoroiodobenzene was used in the preparation of fluorotriphenylene derivatives. 4-[F] Fluoroiodobenzene is a versatile building block in 18F radiochemistry and is used in various transition metal-mediated C-C and C-N cross-coupling reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Aplicaciones
Se utilizó 4-fluoroyodobenceno en la preparación de derivados del fluorotrifenileno. El 4-[F] fluoroyodobenceno es un bloque de construcción versátil en radioquímica 18 F y se utiliza en varias reacciones de acoplamiento cruzado C-C y C-N mediadas por metales de transición.

Solubilidad
Insoluble en agua.

Notas
Sensible a la luz. Almacenar en lugar fresco y seco. Mantener el recipiente herméticamente cerrado.
RUO – Research Use Only

General References:

  1. Jerry M. Meyersa.; Andrew J. Gellman. Effect of substituents on the phenyl coupling reaction on Cu(111).Surface Science. 1995, 337 (1-2), 40-50.
  2. Hülya Akgün.; Tomas Hudlicky. Total syntheses of ert-conduramine A and ent-7-deoxypancratistatin. Tetrahedron Lett. 1999, 40 (16),3081-3084.
  3. Regioselective metallation can be accomplished with LDA ortho to the fluoro substituent: Tetrahedron Lett., 33, 7499 (1992). Subsequent carboxylation and F - displacement with an amine has been used to synthesize 5-iodoanthranilic acid derivatives: J. Med. Chem., 40, 717 (1997).