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2-Bromo-6-metoxinaftaleno, 98 %, Thermo Scientific Chemicals
2-Bromo-6-metoxinaftaleno, 98 %, Thermo Scientific Chemicals
2-Bromo-6-metoxinaftaleno, 98 %, Thermo Scientific Chemicals
Thermo Scientific Chemicals

2-Bromo-6-metoxinaftaleno, 98 %, Thermo Scientific Chemicals

CAS: 5111-65-9 | C11H9BrO | 237.096 g/mol
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Cantidad:
10 g
50 g
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Número de catálogo A19450.18
también denominado A19450-18
Precio (EUR)
159,00
Each
Cantidad:
50 g
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Precio (EUR)
159,00
Each
Identificadores químicos
CAS5111-65-9
IUPAC Name2-bromo-6-methoxynaphthalene
Molecular FormulaC11H9BrO
InChI KeyAYFJBMBVXWNYLT-UHFFFAOYSA-N
SMILESCOC1=CC=C2C=C(Br)C=CC2=C1
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EspecificacionesSpecification SheetHoja de especificaciones
Appearance (Color)White to cream or pale pink
Melting Point (clear melt)104.0-110.0?C
FormPowder
Assay (GC)≥97.5%
2-Bromo-6-methoxynaphthalene is used in the synthesis of nabumetone [4-(6-methoxy-2-naphthalenyl)-2-butanone] by Heck reaction.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Aplicaciones
El 2-bromo-6-metoxinaftaleno se utiliza en la síntesis de nabumetona [4-(6-metoxi-2-naftalenil)-2-butanona] por reacción de Heck.

Solubilidad
Soluble en DMSO. No soluble en agua.

Notas
Almacenar lejos de agentes oxidantes fuertes. Mantener el recipiente herméticamente cerrado. Almacénese en un lugar fresco y seco en recipientes herméticos.
RUO – Research Use Only

General References:

  1. Howard Alper.; Nathalie Hamel. Asymmetric synthesis of acids by the palladium-catalyzed hydrocarboxylation of olefins in the presence of (R)-(-)- or (S)-(+)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate. J. Am. Chem. Soc. 1990, 112, (7), 2803-2804.
  2. Stephen W. Wright.; David L. Hageman.; Lester D. McClure. Fluoride-Mediated Boronic Acid Coupling Reactions. J. Org. Chem. 1994, 59, (20), 6095-6097.
  3. Undergoes highly efficient, phosphine-free Suzuki coupling reactions with arylboronic acids in water, catalyzed by Pd(II) acetate in the presence of TBAB and potassium carbonate: J. Org. Chem., 62, 7170 (1997).