Yodoacetato de etilo, 98 %, Thermo Scientific Chemicals

Name: Yodoacetato de etilo, 98 %, Thermo Scientific Chemicals
SKU: B24177.06

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5 g

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100 g

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Número de catálogo B24177.06

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Identificadores químicos

CAS623-48-3

IUPAC Nameethyl 2-iodoacetate

Molecular FormulaC4H7IO2

InChI KeyMFFXVVHUKRKXCI-UHFFFAOYSA-N

SMILESCCOC(=O)CI

Especificaciones Specification Sheet

Hoja de especificaciones

FormLiquid

StabilizerCopper wire

Appearance (Color)Clear colorless or pale yellow to orange

Assay (GC)≥97.0%

Refractive Index1.5020-1.5070 @ 20?C

Ethyl iodoacetate was used in the synthesis of trans-2,3-disubstituted indolines by reacting with 1-azido-2-allylbenzene derivatives via a diastereoselective radical cascade.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Aplicaciones
El yodoacetato de etilo se utilizaba en la síntesis de indolinas trans-2,3-disustituidas al reaccionar con derivados de 1-azido-2-alilbenceno a través de una reacción en cascada radicalaria diastereoselectiva.

Solubilidad
Insoluble en agua.

Notas
Sensible a la luz. Almacenar en oscuridad. La temperatura de almacenamiento es de 2-8 °C. Almacenar alejado de agentes oxidantes.

RUO – Research Use Only

General References:

François Brucelle; Philippe Renaud. Synthesis of a leucomitosane via a diastereoselective radical cascade. Journal of Organic Chemistry. 2013, 78, (12), 6245-6252.
Pier Giorgio Cozzi; Alessandro Mignogna and Paola Vicennati. Dimethylzinc-Mediated, Oxidatively Promoted Reformatsky Reaction of Ethyl Iodoacetate with Aldehydes and Ketones. Advanced Synthesis & Catalysis. 2008, 300, (7-8), 975-978.