Fenilglioxilato de etilo, 98 %, Thermo Scientific Chemicals
Fenilglioxilato de etilo, 98 %, Thermo Scientific Chemicals
Fenilglioxilato de etilo, 98 %, Thermo Scientific Chemicals
Thermo Scientific Chemicals

Fenilglioxilato de etilo, 98 %, Thermo Scientific Chemicals

CAS: 1603-79-8 | C10H10O3 | 178.19 g/mol
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Cantidad:
5 g
25 g
100 g
Número de catálogo B25292.06
también denominado B25292-06
Precio (EUR)
28,20
Each
Cantidad:
5 g
Pedido a granel o personalizado
Precio (EUR)
28,20
Each
Identificadores químicos
CAS1603-79-8
IUPAC Nameethyl 2-oxo-2-phenylacetate
Molecular FormulaC10H10O3
InChI KeyQKLCQKPAECHXCQ-UHFFFAOYSA-N
SMILESCCOC(=O)C(=O)C1=CC=CC=C1
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EspecificacionesSpecification SheetHoja de especificaciones
Identification (FTIR)Conforms
Refractive Index1.5135-1.5175 @ 20°C
Appearance (Color)Clear colorless to yellow
FormLiquid
Assay (GC)≥96.0%
Ethyl phenylglyoxylate has been used in preparation of 1,5-dihydro-5-deazaflavin derivatives possessing a chiral substituent at N(3) position.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Aplicaciones
El fenilglioxilato de etilo se ha utilizado en la preparación de derivados de 1,5-dihidro-5-deazaflavina, que presentan un sustituyente quiral en posición N(3).

Solubilidad
Soluble en agua 1143 mg/l a 25 °C.

Notas
Almacenar en un lugar fresco. Mantenga el recipiente bien cerrado en un lugar seco y bien ventilado. Incompatible con agentes oxidantes fuertes.
RUO – Research Use Only

General References:

  1. Kiyoshi Tanaka; Tomoya Okada; Fumio Yoneda; Tomohisa Nagamatsu; Kazunori Kuroda. Preparation of chiral 5-deazaflavin derivatives and their asymmetric reduction of ethyl benzoylformate. Tetrahedron Letters. 1984, 25 (16), 1741-1742.
  2. Mária Sutyinszki; Kornél Szöri; Károly Felföldi; Mihály Bartók. 98% Enantioselectivity in the asymmetric synthesis of a useful chiral building block by heterogeneous method: Enantioselective hydrogenation of ethyl-benzoylformate over cinchona modified Pt/Al2O3 catalysts in the acetic acid. Catalysis Communications. 2002, 3 (3), 125-127.