Ethyl phenylglyoxylate has been used in preparation of 1,5-dihydro-5-deazaflavin derivatives possessing a chiral substituent at N(3) position.
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Aplicaciones
El fenilglioxilato de etilo se ha utilizado en la preparación de derivados de 1,5-dihidro-5-deazaflavina, que presentan un sustituyente quiral en posición N(3).
Solubilidad
Soluble en agua 1143 mg/l a 25 °C.
Notas
Almacenar en un lugar fresco. Mantenga el recipiente bien cerrado en un lugar seco y bien ventilado. Incompatible con agentes oxidantes fuertes.
RUO – Research Use Only
General References:
- Kiyoshi Tanaka; Tomoya Okada; Fumio Yoneda; Tomohisa Nagamatsu; Kazunori Kuroda. Preparation of chiral 5-deazaflavin derivatives and their asymmetric reduction of ethyl benzoylformate. Tetrahedron Letters. 1984, 25 (16), 1741-1742.
- Mária Sutyinszki; Kornél Szöri; Károly Felföldi; Mihály Bartók. 98% Enantioselectivity in the asymmetric synthesis of a useful chiral building block by heterogeneous method: Enantioselective hydrogenation of ethyl-benzoylformate over cinchona modified Pt/Al2O3 catalysts in the acetic acid. Catalysis Communications. 2002, 3 (3), 125-127.