1-Iodo-2-(trimethylsilyl)acetylene may be used to investigate the reactivity of diamagnetic cobalt(I) complex, Tol-BDI((2-pp)2)Co [Tol-BDI((2-pp)2)H = 2-(4-tolyl)-1,3-bis(2-isopropylpyridyl)propenediimine]. It may be used for the synthesis of 1-(4-trimethylsilanylbuta-1,3-diynyl)pyrene, via Pd-coupling with 1-iodo-2-trimethylsilylacetylene.
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Aplicaciones
El 1-yodo-2-(trimetilsilil)acetileno puede usarse para investigar la reactividad del complejo de cobalto(I) diamagnético, Tol-BDI((2-pp)2)Co [Tol-BDI((2-pp)2)H = 2-(4-tolyl)-1,3-bis(2-isopropilpiridil)propenodiimina]. Se puede utilizar para la síntesis de 1-(4-trimetilsilanilbuta-1,3-diinil)pireno, mediante acoplamiento de Pd con 1-yodo-2-trimetilsililacetileno.
Notas
Sensible a la luz. Incompatible con agentes oxidantes.
RUO – Research Use Only
General References:
- Lunhan Ding; Susan V.Olesik. Synthesis of polymer nanospheres and carbon nanospheres using the monomer 1,8-dihydroxymethyl-1,3,5,7- octatetrayne. Nano Letters. 2004, 4, (11),2271-2276
- Elodie E.Marlier; Bridget A.Ulrich; Kristopher McNeill. Synthesis and reactivity of an isolable cobalt(I) complex containing a β-diketiminate-based acyclic tetradentate ligand. Inorg. Chem. 2012, 51, (4),2079-2085