Fluorene is used in the preparation of dyes such as 2,7-diiodofluorene, 2-aminofluorene and 3,6-bis-(dimethylamino)fluorine as well as resins. It acts as a precursor to other fluorene compounds and to prepare fluorenone. It is utilized in the study of the extraction of specific semiconducting single-wall carbon nanotubes. Its polymer, polyfluorene finds application in electrically conductive and electroluminescent as well as in solar cells. In addition to this, it is used as a luminophore inorganic light-emitting diodes
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Aplicaciones
El fluoreno se utiliza en la preparación de colorantes como 2,7-diyodofluoreno, 2-aminofluoreno y 3,6-bis-(dimetilamino)flúor, así como resinas. Actúa como precursor de otros compuestos de fluoreno y para preparar fluorenona. Se utiliza en el estudio de la extracción de nanotubos de carbono de pared única semiconductores específicos. Su polímero, el polifluoreno, se aplica en células eléctricamente conductoras y electroluminiscentes, así como en células solares. Asimismo, se utiliza como luminóforo inorgánico de diodos emisores de luz
Solubilidad
Soluble en alcohol caliente, éter, benceno y ácido acético glacial. Insoluble en agua.
Notas
Incompatibles con agentes oxidantes fuertes.
RUO – Research Use Only
General References:
- Michael addition at C-9 to ɑß-unsaturated ketones or esters occurs using TBAF as base; reaction is very slow using classical bases: Synthesis, 164 (1984).
- Pietropaolo, A.; Wang, Y.; Nakano, T. Predicting the Switchable Screw Sense in Fluorene-Based Polymers. Angew. Chem. Int. Ed. 2015, 127 (9), 2726-2730.
- Chen, Z.; Liang, J.; Han, X.; Yin, J.; Yu, G. A.; Liu, S. H. Fluorene-based novel highly emissive fluorescent molecules with aggregate fluorescence change or aggregation-induced emission enhancement characteristics. Dyes Pigm. 2015, 112, 59-66.