α-Methylstyrene (AMS) is used in the synthesis of (acrylonitrile-styrene-acrylic copolymer)/(α-methylstyrene-acrylonitrile copolymer). It is used in the manufacture of plasticizers, resins and polymers.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Aplicaciones
El α-metilestireno (AMS) se utiliza en la síntesis de (copolímero acrilonitrilo-estireno-acrílico)/(copolímero α-metilestireno-acrilonitrilo). Se utiliza en la fabricación de plastificantes, resinas y polímeros.
Solubilidad
Soluble en agua.(0,1 g/l) a 25 °C.
Notas
Almacenar a 4 °C. Los materiales incompatibles son agentes oxidantes fuertes, peróxidos, compuestos organometálicos y sales metálicas.
RUO – Research Use Only
General References:
- Ray L. Sweany; Jack Halpern. Hydrogenation of .alpha.-methylstyrene by hydridopentacarbonylmanganese (I). Evidence for a free-radical mechanism.J. Am. Chem. Soc.1977, 99 (25), 8335-8337.
- Toshinobu Higashimura; Masami Kamigaito; Makoto Kato; Toshiyuki Hasebe; Mitsuo Sawamoto.Macromolecules.1977, 26 (11), 2670-2673.
- For asymmetric ene-reaction with methyl glyoxylate, catalyzed by a chiral binaphthyl (see (R)-(+)-1,1'-Bi(2-naphthol) , L08305) Ti(O-i-Pr)4 complex to give methyl (2R)-3-hydroxy-4-phenyl-4-pentenoate, see: Org. Synth. Coll., 9, 596 (1998):
- In the presence of trichloroacetic acid, has been reported for the protection of 5-substituted tetrazoles as their N-cumyl derivatives. Deprotection was effected by catalytic transfer hydrogenolysis: J. Org. Chem., 64, 9301 (1999).