Thermo Scientific Chemicals

Iodomethane, 99%, stab. with copper, Thermo Scientific Chemicals

Catalog number: A10559.18
50 g, Each
Thermo Scientific Chemicals

Iodomethane, 99%, stab. with copper, Thermo Scientific Chemicals

Catalog number: A10559.18
50 g, Each
Quantity
Catalog number: A10559.18
also known as A10559-18
Price (EUR)
Price: 43,40
Your price:
Quantity
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Chemical Identifiers

CAS
74-88-4
IUPAC Name
iodomethane
Molecular Formula
CH3I
InChI Key
INQOMBQAUSQDDS-UHFFFAOYSA-N
SMILES
CI
Assay (GC)
≥98.5% (non-U.S. specification)
Identification (FTIR)
Conforms (non-U.S. specification)
Assay from Suppliers CofA
≥98.5% (U.S. specification)
Stabilizer
Copper
Appearance (Color)
Clear colorless to pale yellow to pale pink

Description

Iodomethane is a methylating agent used for alkylating carbon, oxygen, sulfur, nitrogen and phosphorus nucleophiles. For example, phenol reacts with methyl iodide to give anisole. In the Monsanto process, the insitu formed iodomethane reacts with carbon monoxide in the presence of a rhodium complex to give acetyl iodide, which on hydrolysis yields acetic acid. It reacts with magnesium to form the Grignard reagent, methylmagnesium iodide used in organic synthesis. It finds applications as an intermediate in the manufacture of pharmaceuticals and in phase transfer catalysts.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Iodomethane is a methylating agent used for alkylating carbon, oxygen, sulfur, nitrogen and phosphorus nucleophiles. For example, phenol reacts with methyl iodide to give anisole. In the Monsanto process, the insitu formed iodomethane reacts with carbon monoxide in the presence of a rhodium complex to give acetyl iodide, which on hydrolysis yields acetic acid. It reacts with magnesium to form the Grignard reagent, methylmagnesium iodide used in organic synthesis. It finds applications as an intermediate in the manufacture of pharmaceuticals and in phase transfer catalysts.

Solubility
Miscible with water.

Notes
Light and moisture sensitive. Store in cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents, strong bases and oxygen.
RUO – Research Use Only

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    Safety and Handling


    Classification of the substance or mixture
    CLP classification - Regulation(EC) No 1272/2008
    Acute oral toxicity
    Category 3
    Acute dermal toxicity
    Category 4
    Acute Inhalation Toxicity - Vapors
    Category 3
    Skin Corrosion/Irritation
    Category 2
    Carcinogenicity
    Category 2
    Specific target organ toxicity - (single exposure)
    Category 3
    Label Elements
    Signal Word

    Danger

    Hazard Statements

    H301 + H331 - Toxic if swallowed or if inhaled

    H312 - Harmful in contact with skin

    H315 - Causes skin irritation

    H335 - May cause respiratory irritation

    H351 - Suspected of causing cancer

    Precautionary Statements

    P201 - Obtain special instructions before use

    P280 - Wear protective gloves/protective clothing/eye protection/face protection

    P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

    P302 + P352 - IF ON SKIN: Wash with plenty of soap and water

    P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing

    P311 - Call a POISON CENTER or doctor/physician