Thermo Scientific Chemicals

Terephthaloyl chloride, 99%, Thermo Scientific Chemicals

Catalog number: A11224.30
250 g, Each
Thermo Scientific Chemicals

Terephthaloyl chloride, 99%, Thermo Scientific Chemicals

Catalog number: A11224.30
250 g, Each
Quantity
Catalog number: A11224.30
also known as A11224-30
Price (EUR)
Quantity
-

Chemical Identifiers

CAS
100-20-9
IUPAC Name
benzene-1,4-dicarbonyl dichloride
Molecular Formula
C8H4Cl2O2
InChI Key
LXEJRKJRKIFVNY-UHFFFAOYSA-N
SMILES
ClC(=O)C1=CC=C(C=C1)C(Cl)=O
Appearance (Color)
White
Form
crystalline flakes or powder
Assay (GC)
> 98.5%
Assay (Titration ex Chloride)
> 98.5%

Description

Terephthaloyl chloride acts as a monomer with p-phenylenediamine used in the preparation of polymer viz. poly paraphenylene terephthalamide. It is an active component in performance polymers and aramid fibers, which gives flame resistance, chemical resistance, temperature stability, light weight, and very high strength. It is also used as an effective water scavenger, utilized to stabilize isocyanates and urethane prepolymers. Further, it is used in the preparation of liquid crystalline thermosets by thermal cyclotrimerization of dicyanate compounds of ring substituted bis(4-hydroxyphenyl) terepthalates. In addition to this, it is involved in the condensation reaction with difunctional alfa, μ-diaminopolystyrene to get chain-extended polystyrene containing amide bonds along the polymer backbone.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Terephthaloyl chloride acts as a monomer with p-phenylenediamine used in the preparation of polymer viz. poly paraphenylene terephthalamide. It is an active component in performance polymers and aramid fibers, which gives flame resistance, chemical resistance, temperature stability, light weight, and very high strength. It is also used as an effective water scavenger, utilized to stabilize isocyanates and urethane prepolymers. Further, it is used in the preparation of liquid crystalline thermosets by thermal cyclotrimerization of dicyanate compounds of ring substituted bis(4-hydroxyphenyl) terepthalates. In addition to this, it is involved in the condensation reaction with difunctional alfa, µ-diaminopolystyrene to get chain-extended polystyrene containing amide bonds along the polymer backbone.

Solubility
Soluble in ethanol, ether and other common organic solvents.

Notes
Incompatible with alcohols, oxidizing agents, water and strong bases.
RUO – Research Use Only

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    Safety and Handling


    Classification of the substance or mixture
    CLP classification - Regulation(EC) No 1272/2008
    Acute Inhalation Toxicity - Dusts and Mists
    Category 3
    Skin Corrosion/Irritation
    Category 1
    Serious Eye Damage/Eye Irritation
    Category 1
    Label Elements
    Signal Word

    Danger

    Hazard Statements

    H314 - Causes severe skin burns and eye damage

    H331 - Toxic if inhaled

    Precautionary Statements

    P280 - Wear protective gloves/protective clothing/eye protection/face protection

    P301 + P330 + P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

    P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower

    P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing

    P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

    P310 - Immediately call a POISON CENTER or doctor/physician