Thermo Scientific Chemicals

2-Aminobenzyl alcohol, 98%, Thermo Scientific Chemicals

Catalog number: A13180.18
50 g, Each
Thermo Scientific Chemicals

2-Aminobenzyl alcohol, 98%, Thermo Scientific Chemicals

Catalog number: A13180.18
50 g, Each
Quantity
Catalog number: A13180.18
also known as A13180-18
Price (EUR)
Price: 77,80
Online price: 70,02
Your price:
Quantity
-

Chemical Identifiers

CAS
5344-90-1
IUPAC Name
(2-aminophenyl)methanol
Molecular Formula
C7H9NO
InChI Key
VYFOAVADNIHPTR-UHFFFAOYSA-N
SMILES
NC1=CC=CC=C1CO
Identification (FTIR)
Conforms
Melting Point
81.0-86.0°C
Form
Crystals or powder or crystalline powder
Appearance (Color)
White to cream to yellow to brown
Assay (GC)
≥97.5%

Description

2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde. was used in the synthesis of ethyl 2-hydroxymethylcarbanilate.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde. was used in the synthesis of ethyl 2-hydroxymethylcarbanilate.

Solubility
Very soluble in water.

Notes
Store at room temperature. Incompatible with oxidizing agents.
RUO – Research Use Only

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    Safety and Handling


    Classification of the substance or mixture
    CLP classification - Regulation(EC) No 1272/2008
    Acute oral toxicity
    Category 4
    Skin Corrosion/Irritation
    Category 2
    Serious Eye Damage/Eye Irritation
    Category 2
    Specific target organ toxicity - (single exposure)
    Category 3
    Label Elements
    Signal Word

    Warning

    Hazard Statements

    H302 - Harmful if swallowed

    H315 - Causes skin irritation

    H319 - Causes serious eye irritation

    H335 - May cause respiratory irritation

    Precautionary Statements

    P261 - Avoid breathing dust/fume/gas/mist/vapors/spray

    P280 - Wear protective gloves/protective clothing/eye protection/face protection

    P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

    P302 + P352 - IF ON SKIN: Wash with plenty of soap and water

    P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing