2-Bromo-4'-methoxyacetophenone, 98%

Name: 2-Bromo-4'-methoxyacetophenone, 98%
SKU: A13415.22
Price: 342.00 EUR

CAS: 2632-13-5 | C9H9BrO2 | 229.07 g/mol

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Catalog number A13415.22

also known as A13415-22

Price (EUR)

342,00

Each

Quantity:

100 g

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Price (EUR)

342,00

Each

Chemical Identifiers

CAS2632-13-5

IUPAC Name2-bromo-1-(4-methoxyphenyl)ethan-1-one

Molecular FormulaC9H9BrO2

InChI KeyXQJAHBHCLXUGEP-UHFFFAOYSA-N

SMILESCOC1=CC=C(C=C1)C(=O)CBr

Specifications

Specification Sheet

FormCrystals or powder or crystalline powder

Identification (FTIR)Conforms

Assay (GC)≥97.5%

Appearance (Color)White to cream to pale brown

Melting Point (clear melt)67-73?C

2-Bromo-4'-methoxyacetophenone, is used as a cell-permeable, covalent and potent protein tyrosine phosphatase inhibitor.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
2-Bromo-4′-methoxyacetophenone, is used as a cell-permeable, covalent and potent protein tyrosine phosphatase inhibitor.

Solubility
It is soluble in DMSO, water (partly miscible), most organic solvents, and methanol.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature: 2 - 8°C

RUO – Research Use Only

General References:

W Zhang.; DP Curran.; CHT Chen. Use of fluorous silica gel to separate fluorous thiol quenching derivatives in solution-phase parallel synthesis. Tetrahedron letters. 2002, 58,(20), 3871-3875.
Y Nishiyama.; A Kobayashi. Synthesis of 1, 4-diketones: reaction of α-bromo ketones with tetrakis (dimethylamino) ethylene (TDAE). Tetrahedron letters. 2006, 47,(31), 5565-5567.
Reagent for protection of carboxylic acids as 4-methoxyphenacyl esters, which may be prepared in the presence of KF as base: Synthesis, 897 (1981) and can be cleaved photolytically: J. Org. Chem., 38, 3771 (1973). Peptide bonds are generally unaffected by irradiation but some cleavage of trityl protecting groups may occur. See also Appendix 6. For further discussion of this and other photo-removable protecting groups, see: Synthesis, 1 (1980); Org. Photochem., 9, 225 (1987).