Thermo Scientific Chemicals

1-Bromo-4-iodobenzene, 98%, Thermo Scientific Chemicals

Catalog number: A13859.18
50 g, Each
Thermo Scientific Chemicals

1-Bromo-4-iodobenzene, 98%, Thermo Scientific Chemicals

Catalog number: A13859.18
50 g, Each
Quantity
Catalog number: A13859.18
also known as A13859-18
Price (EUR)
Price: 162,00
Online price: 145,80
Your price:
Quantity
-

Chemical Identifiers

CAS
589-87-7
IUPAC Name
1-bromo-4-iodobenzene
Molecular Formula
C6H4BrI
InChI Key
UCCUXODGPMAHRL-UHFFFAOYSA-N
SMILES
BrC1=CC=C(I)C=C1
Appearance (Color)
White to cream or pink to brown
Identification (FTIR)
Conforms
Assay (GC)
≥97.5%
Form
Crystalline powder
Melting Point (clear melt)
89-93?C

Description

It is mainly used as the OLED pharmaceutical intermediate, as reagent for in situ desilylation and coupling of silylated alkynes, as substrate in copper-free Sonogashira coupling in aqueous acetone. It is also used in synthesis of β,β,dibromostyrenes, as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids).

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
It is mainly used as the OLED pharmaceutical intermediate, as reagent for in situ desilylation and coupling of silylated alkynes, as substrate in copper-free Sonogashira coupling in aqueous acetone. It is also used in synthesis of β,β,dibromostyrenes, as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids).

Solubility
Insoluble in water.

Notes
Light sensitive. Store in a cool, dry, well-ventilated area. Store away from oxidizing agent, light.
RUO – Research Use Only

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    Safety and Handling


    Classification of the substance or mixture
    CLP classification - Regulation(EC) No 1272/2008
    Skin Corrosion/Irritation
    Category 2
    Serious Eye Damage/Eye Irritation
    Category 2
    Specific target organ toxicity - (single exposure)
    Category 3
    Label Elements
    Signal Word

    Warning

    Hazard Statements

    H315 - Causes skin irritation

    H319 - Causes serious eye irritation

    H335 - May cause respiratory irritation

    Precautionary Statements

    P261 - Avoid breathing dust/fume/gas/mist/vapors/spray

    P280 - Wear protective gloves/protective clothing/eye protection/face protection

    P302 + P352 - IF ON SKIN: Wash with plenty of soap and water

    P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing