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1-Bromo-2-iodobenzene, 98+%, stab. with copper
1-Bromo-2-iodobenzene, 98+%, stab. with copper
1-Bromo-2-iodobenzene, 98+%, stab. with copper
Thermo Scientific Chemicals

1-Bromo-2-iodobenzene, 98+%, stab. with copper

CAS: 583-55-1 | C6H4BrI | 282.906 g/mol
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Catalog number A17020.06
also known as A17020-06
Price (EUR)
33,70
Each
Quantity:
5 g
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Price (EUR)
33,70
Each
Chemical Identifiers
CAS583-55-1
IUPAC Name1-bromo-2-iodobenzene
Molecular FormulaC6H4BrI
InChI KeyOIRHKGBNGGSCGS-UHFFFAOYSA-N
SMILESBrC1=CC=CC=C1I
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SpecificationsSpecification SheetSpecification Sheet
Refractive Index1.6625-1.6675 @ 20?C
Appearance (Color)Clear colorless to yellow to brown
Identification (FTIR)Conforms
Assay (GC)≥98.0%
FormLiquid
2-Bromoiodobenzene is used in the synthesis of diarylamines.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
2-Bromoiodobenzene is used in the synthesis of diarylamines.

Solubility
Not miscible or difficult to mix in water.

Notes
Light Sensitive. Protect from light. Store away from oxidizing agents.
RUO – Research Use Only

General References:

  1. María E Budén.; Victoria A Vaillard.; Sandra E Martin.; Roberto A Rossi. Synthesis of carbazoles by intramolecular arylation of diarylamide anions.J Org Chem.2009,74(12), 4490-4498.
  2. Biao Lu.; Bao Wang.; Yihua Zhang.; and Dawei Ma. CuI-Catalyzed Domino Process to 2,3-Disubstituted Benzofurans from 1-Bromo-2-Iodobenzenes and β-Keto Esters.J. Org. Chem.,2007,72,(14), 5337-5341.
  3. Benzyne precursor. In the presence of excess of a Grignard reagent, the initially formed benzyne undergoes nucleophilic addition to give an ortho-substituted phenylmagnesium halide: Synth. Commun., 18, 1749 (1988).
  4. Regioselective Suzuki coupling with arylboronic acids has been achieved giving 2-bromobiphenyl derivatives: Synlett, 207 (1992).