Search Thermo Fisher Scientific
Element Search
Structure SearchThermo Scientific Chemicals
Benzyl isocyanate, 98%, Thermo Scientific Chemicals
Catalog number: L02633.03
1 g, Each
Thermo Scientific Chemicals
Benzyl isocyanate, 98%, Thermo Scientific Chemicals
Catalog number: L02633.03
1 g, Each
Quantity
Catalog number: L02633.03
also known as L02633-03
Price (EUR)
Price: 23,30
Online price: 20,97
Your price:
Quantity
-
Chemical Identifiers
CAS
3173-56-6
IUPAC Name
(isocyanatomethyl)benzene
Molecular Formula
C8H7NO
InChI Key
YDNLNVZZTACNJX-UHFFFAOYSA-N
SMILES
O=C=NCC1=CC=CC=C1
Specifications
Specification SheetAppearance (Color)
Clear, colourless to pale yellow
Form
liquid
Refractive Index
1.5230 - 1.5270 @20?C
Assay (GC)
> 97.5%
Description
Benzyl isocyanate, is used as a protected ammonia equivalent in the stereo selective ring-opening of chiral 2,3-epoxy alcohols (from Sharpless asymmetric epoxidation). The key step in the sequence involves intramolecular cyclization of the carbamate intermediate. It is also used in a multicomponent, stereospecific synthesis of 1,3-oxazinane-2,4-diones employing an Al-salph complex.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Benzyl isocyanate, is used as a protected ammonia equivalent in the stereo selective ring-opening of chiral 2,3-epoxy alcohols (from Sharpless asymmetric epoxidation). The key step in the sequence involves intramolecular cyclization of the carbamate intermediate. It is also used in a multicomponent, stereospecific synthesis of 1,3-oxazinane-2,4-diones employing an Al-salph complex.
Solubility
It hydrolyzes with water.
Notes
Moisture & heat Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from alcohols, amines.
Benzyl isocyanate, is used as a protected ammonia equivalent in the stereo selective ring-opening of chiral 2,3-epoxy alcohols (from Sharpless asymmetric epoxidation). The key step in the sequence involves intramolecular cyclization of the carbamate intermediate. It is also used in a multicomponent, stereospecific synthesis of 1,3-oxazinane-2,4-diones employing an Al-salph complex.
Solubility
It hydrolyzes with water.
Notes
Moisture & heat Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from alcohols, amines.
RUO – Research Use Only
Figures
Documents & Downloads
Certificates
Search by lot number or partial lot number
Frequently asked questions (FAQs)
Citations & References
Search citations by name, author, journal title or abstract text
Safety and Handling
Classification of the substance or mixture
CLP classification - Regulation(EC) No 1272/2008
Flammable liquids
Category 3
Acute oral toxicity
Category 3
Acute dermal toxicity
Category 3
Acute Inhalation Toxicity - Dusts and Mists
Category 3
Skin Corrosion/Irritation
Category 2
Serious Eye Damage/Eye Irritation
Category 2
Specific target organ toxicity - (single exposure)
Category 3
Label Elements
Signal Word
Danger
Hazard Statements
H301 + H311 + H331 - Toxic if swallowed, in contact with skin or if inhaled
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H335 - May cause respiratory irritation
Physical Hazards
H226 - Flammable liquid and vapor
Precautionary Statements
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P302 + P350 - IF ON SKIN: Gently wash with plenty of soap and water
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 - Call a POISON CENTER or doctor if you feel unwell