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1-Chloroethyl chloroformate, 98%, Thermo Scientific Chemicals
Catalog number: L14197.06
5 g, Each
Thermo Scientific Chemicals
1-Chloroethyl chloroformate, 98%, Thermo Scientific Chemicals
Catalog number: L14197.06
5 g, Each
Quantity
Catalog number: L14197.06
also known as L14197-06
Price (EUR)
26,28 Online price
29,20
Each
Quantity
-
Chemical Identifiers
CAS
50893-53-3
Specifications
Specification SheetAppearance (Color)
Clear colorless
Assay from Supplier's CofA
≥97.5% (U.S. sourced material)
Refractive Index
1.4215-1.4255 @ 20°C (non-U.S. sourced material)
Form
Liquid
Comment
Material Sourced in the U.S. and in other countries
Description
1-Chloroethyl chloroformate acts as a reagent in the selective N-dealkylation of tertiary amines. It is also used as a reactant in the preparation of alkyl 1-chloroethyl carbonates. Further, it is used for N-demethylation reaction in the determination of multiple drugs of abuse in biological fluids using capillary electrophoresis with native fluorescence and laser-induced fluorescence detection. It plays an important role as a catalyst for the chemoselective desilylation of silyl-protected alcohols. In addition to this, it is used to cleave benzhydryl groups from amines.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
1-Chloroethyl chloroformate acts as a reagent in the selective N-dealkylation of tertiary amines. It is also used as a reactant in the preparation of alkyl 1-chloroethyl carbonates. Further, it is used for N-demethylation reaction in the determination of multiple drugs of abuse in biological fluids using capillary electrophoresis with native fluorescence and laser-induced fluorescence detection. It plays an important role as a catalyst for the chemoselective desilylation of silyl-protected alcohols. In addition to this, it is used to cleave benzhydryl groups from amines.
Solubility
Miscible with most organic solvents.
Notes
Moisture sensitive. Store in a cool place. Incompatible with strong oxidizing agent, strong base, alcohols and amines.
1-Chloroethyl chloroformate acts as a reagent in the selective N-dealkylation of tertiary amines. It is also used as a reactant in the preparation of alkyl 1-chloroethyl carbonates. Further, it is used for N-demethylation reaction in the determination of multiple drugs of abuse in biological fluids using capillary electrophoresis with native fluorescence and laser-induced fluorescence detection. It plays an important role as a catalyst for the chemoselective desilylation of silyl-protected alcohols. In addition to this, it is used to cleave benzhydryl groups from amines.
Solubility
Miscible with most organic solvents.
Notes
Moisture sensitive. Store in a cool place. Incompatible with strong oxidizing agent, strong base, alcohols and amines.
RUO – Research Use Only
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Safety and Handling
Classification of the substance or mixture
CLP classification - Regulation(EC) No 1272/2008
Flammable liquids
Category 3
Acute oral toxicity
Category 4
Acute Inhalation Toxicity - Vapors
Category 2
Skin Corrosion/Irritation
Category 1
Serious Eye Damage/Eye Irritation
Category 1
Label Elements
Signal Word
Danger
Hazard Statements
H302 - Harmful if swallowed
H314 - Causes severe skin burns and eye damage
H330 - Fatal if inhaled
Physical Hazards
H226 - Flammable liquid and vapor
EU Specific Hazard Statements
EUH029 - Contact with water liberates toxic gas
Precautionary Statements
P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P402 + P404 - Store in a dry place. Store in a closed container
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P280 - Wear eye protection/ face protection
P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician