Sodium tert-pentyloxide, 95%

Name: Sodium tert-pentyloxide, 95%
SKU: L15112.22

CAS: 14593-46-5 | C5H11NaO | 110.132 g/mol

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Catalog number L15112.22

also known as L15112-22

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Quantity:

100 g

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Chemical Identifiers

CAS14593-46-5

IUPAC Namesodium 2,2-dimethylpropan-1-olate

Molecular FormulaC5H11NaO

InChI KeyYQMLGVNRTAQUFQ-UHFFFAOYSA-N

SMILES[Na+].CC(C)(C)C[O-]

Specifications

Specification Sheet

Appearance (Color)White to yellow to brown

FormPowder or crystalline powder

Assay (Non-aqueous acid-base Titration)≥94.0%

Sodium tert-pentyloxide is a effective base for the alkylation of ketones.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Sodium tert-pentyloxide is a effective base for the alkylation of ketones.

Solubility
Reacts with water.

Notes
Air and Moisture Sensitive, store away form air and water/moisture. Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

RUO – Research Use Only

General References:

I. N. Nazarov; S. N. Ananchenko; I. V. Torgov. Condensation of 1-vinylcyclohexene with propiolic and tetrolic acids and esters. Bulletin of the Academy of Sciences of the USSR, Division of chemical science.1959, 8,(1), 84-90.
Strong, hydrocarbon-soluble base: J. Organomet. Chem., 364, 281 (1989). Useful base for the Wittig reaction: Tetrahedron Lett., 31, 635 (1990).
In combination with LDA forms a 'superbasic ' reagent: Synthesis, 1493 (1995).