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Thermo Scientific Chemicals
Glutaronitrile, 99%
CAS: 544-13-8 | C5H6N2 | 94.117 g/mol
化学物質識別子
CAS544-13-8
IUPAC Namepentanedinitrile
Molecular FormulaC5H6N2
InChI KeyZTOMUSMDRMJOTH-UHFFFAOYSA-N
SMILESN#CCCCC#N
さらに表示
仕様
スペックシート
スペックシートFormLiquid
Assay (GC)≥98.5%
Appearance (Color)Clear colorless to pale yellow
Refractive Index1.4335-1.4365 @ 20?C
It can be used for the conversion, by exchange, of carboxylic acids to nitriles, by heating in the presence of phosphoric acid. The equilibrium is displaced by cyclization to glutarimide. It is also used in the preparation of dicarbonyl compounds.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
It can be used for the conversion, by exchange, of carboxylic acids to nitriles, by heating in the presence of phosphoric acid. The equilibrium is displaced by cyclization to glutarimide. It is also used in the preparation of dicarbonyl compounds.
Solubility
Soluble in water, alcohol and chloroform.
Notes
Hygroscopic. Protect from water/moisture and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
It can be used for the conversion, by exchange, of carboxylic acids to nitriles, by heating in the presence of phosphoric acid. The equilibrium is displaced by cyclization to glutarimide. It is also used in the preparation of dicarbonyl compounds.
Solubility
Soluble in water, alcohol and chloroform.
Notes
Hygroscopic. Protect from water/moisture and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
RUO – Research Use Only
General References:
- Yaser Abu-Lebdeh, et al. New electrolytes based on glutaronitrile for high energy/power Li-ion batteries.J. Power Sources.,2009,189(1), 576-579.
- Jae-Young Lee, et al. Characteristics of the DGEBA/MDA system modified with glutaronitrile.Mater. Chem. Phys.,1996,44(1), 74-78.
- Can be used for the conversion, by exchange, of carboxylic acids to nitriles, by heating in the presence of phosphoric acid. The equilibrium is displaced by cyclization to glutarimide: J. Org. Chem., 36, 3050 (1971).