Methyl methoxyacetate, 99%

Name: Methyl methoxyacetate, 99%
SKU: B22528.36

CAS: 6290-49-9 | C4H8O3 | 104.11 g/mol

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Catalog number B22528.36

also known as B22528-36

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500 g

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Chemical Identifiers

CAS6290-49-9

IUPAC Namemethyl 2-methoxyacetate

Molecular FormulaC4H8O3

InChI KeyQRMHDGWGLNLHMN-UHFFFAOYSA-N

SMILESCOCC(=O)OC

Specifications

Specification Sheet

Assay (GC)≥98.5%

Identification (FTIR)Conforms

Refractive Index1.3955-1.3985 @ 20?C

Appearance (Color)Clear colorless

FormLiquid

Methyl methoxyacetate is used in the preparation of 4-hydroxy-2-mercapto-5-methoxypyrimidine (II).

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Methyl methoxyacetate is used in the preparation of 4-hydroxy-2-mercapto-5-methoxypyrimidine (II).

Solubility
Soluble in water.

Notes
Keep container tightly closed. Store away from oxidizing agents.

RUO – Research Use Only

General References:

Qiuhua Li.; Chuanhui Huang.; Tongwen Xu. Bipolar membrane electrodialysis in an organic medium: Production of methyl methoxyacetate. Journal of Membrane Science. 2009, 339, (1-2), 28-32.
Qiuhua Li.; Chuanhui Huang.; Tongwen Xu. Alcohol splitting for the production of methyl methoxyacetate: Integration of ion-exchange with bipolar membrane electrodialysis. Journal of Membrane Science. 2011, 367, (1-2), 314-318.
The ɑ-lithio-derivative adds to ketones in the normal manner. Elimination of water provides a useful synthesis of ɑ-methoxyacrylates: Tetrahedron Lett., 2825 (1977).