Chlorodi(p-tolyl)phosphine, 95%

Name: Chlorodi(p-tolyl)phosphine, 95%
SKU: H25889.03

CAS: 1019-71-2 | C14H14ClP | 248.69 g/mol

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Catalog number H25889.03

also known as H25889-03

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Chemical Identifiers

CAS1019-71-2

IUPAC Namechlorobis(4-methylphenyl)phosphane

Molecular FormulaC14H14ClP

InChI KeyBJBXRRHIBSXGLF-UHFFFAOYSA-N

SMILESCC1=CC=C(C=C1)P(Cl)C1=CC=C(C)C=C1

Specifications

Specification Sheet

Proton NMRConforms to structure

Appearance (Color)Clear, colorless to pale yellow

Assay by NMR≥94.0%

FormViscous liquid

Phosphorus-31 NMRConforms to structure

Chlorodi(p-tolyl)phosphine is used as a reactant for synthesis of palladium catalysts for C-C bond forming cross-coupling reactions, ligands for nickel(0)-catalyzed isomerization reactions, phosphinosulfonamide nickel complexes for oligomerization reactions. It is a reactant for phosphinylation reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Chlorodi(p-tolyl)phosphine is used as a reactant for synthesis of palladium catalysts for C-C bond forming cross-coupling reactions, ligands for nickel(0)-catalyzed isomerization reactions, phosphinosulfonamide nickel complexes for oligomerization reactions. It is a reactant for phosphinylation reactions.

Solubility
Reacts with water.

Notes
Air and moisture sensitive. Incompatible with oxidizing agents, water/ moisture.

RUO – Research Use Only

General References:

Chi-Feng Lin; Iwao Ojima. Formal enantioselective total synthesis of schulzeines A-C via Pd-catalyzed intramolecular asymmetric allylic amination. Journal of Organic Chemistry. 2011, 76 (15), 6240-6249.
X. Ren; L. Wang and Y. Li. 1,1'-Bis[bis(4-methoxyphenyl)phosphanyl]ferrocene. Acta Cryst. 2012, 68, 922.