Methyl 3-bromo-4-hydroxybenzoate, 98%
Methyl 3-bromo-4-hydroxybenzoate, 98%
Methyl 3-bromo-4-hydroxybenzoate, 98%
Thermo Scientific Chemicals

Methyl 3-bromo-4-hydroxybenzoate, 98%

CAS: 29415-97-2 | C8H7BrO3 | 231.05 g/mol
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10 g
50 g
Catalog number H30222.09
also known as H30222-09
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Chemical Identifiers
CAS29415-97-2
IUPAC Namemethyl 3-bromo-4-hydroxybenzoate
Molecular FormulaC8H7BrO3
InChI KeyRKUNSPWAQIUGEZ-UHFFFAOYSA-N
SMILESCOC(=O)C1=CC(Br)=C(O)C=C1
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SpecificationsSpecification SheetSpecification Sheet
Appearance (Color)White
Melting Point (clear melt)104.0-110.0?C
Assay (GC)≥97.5%
FormPowder
A reactant used in the preparation of selective inhibitors. In unsymmetrical Ullman reaction between methyl 5bromovanillate (II) and methyl 3-bromo-4-hydroxybenzoate (III) yielded all the three possible dicarbomethoxy-dibenzo-pdioxms which were separated by repeated chromatography over silica gel. A phosphorus- and bromine-containing bifunctional monomer has been prepared from bis(chloromethyl)methylphosphine oxide and the sodium salt of methyl 3-bromo-4-hydroxybenzoate.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
A reactant used in the preparation of selective inhibitors. In unsymmetrical Ullman reaction between methyl 5bromovanillate (II) and methyl 3-bromo-4-hydroxybenzoate (III) yielded all the three possible dicarbomethoxy-dibenzo-pdioxms which were separated by repeated chromatography over silica gel. A phosphorus- and bromine-containing bifunctional monomer has been prepared from bis(chloromethyl)methylphosphine oxide and the sodium salt of methyl 3-bromo-4-hydroxybenzoate.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
RUO – Research Use Only

General References:

  1. H. Sivriev ,; G. Borissov ,; T.E. Kron,; E.N. Tsvetkov,; M.I. Kabachnik. Polyesters based on bromine-containing bis(p-methoxycarbonylphenoxymethyl)-methylphosphine oxide. European Polymer Journal. 15 (8),771-774.
  2. B. Anjaneyulu,; T.R. Govindachari,; N. Viswanathan.Total synthesis of dl-O-methyltiliacorine . Tetrahedron. 1971, 27 (2) , 439-443.