Butadiene monoxide, 98%

Name: Butadiene monoxide, 98%
SKU: L00238.03

CAS: 930-22-3 | C4H6O | 70.091 g/mol

Change view

Quantity:

1 g

5 g

25 g

Try the chem dex^TM web app

Catalog number L00238.03

also known as L00238-03

Price (TWD)

Quantity:

1 g

Request bulk or custom format

Chemical Identifiers

CAS930-22-3

IUPAC Name2-ethenyloxirane

Molecular FormulaC4H6O

InChI KeyGXBYFVGCMPJVJX-UHFFFAOYNA-N

SMILESC=CC1CO1

Specifications

Specification Sheet

Appearance (Color)Clear colorless

Assay (GC)≥97.5%

Refractive Index1.4155-1.4200 @ 20?C

Identification (FTIR)Conforms

FormLiquid

Butadiene monoxide is used as key starting material for the synthesis of (-)-bulgecinine and (+)-broussonetine G.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Butadiene monoxide is used as key starting material for the synthesis of (-)-bulgecinine and (+)-broussonetine G.

Solubility
Miscible with ethanol, ethyl ether, benzene and organic solvents.

Notes
Moisture sensitive. Store in cool place. Incompatible with acids, bases and oxidizing agents.

RUO – Research Use Only

General References:

Reaction with allyl bromide, mediated by In metal, affords diallylmethanol: Tetrahedron Lett., 44, 2911 (2003):
Li, G.; Feng, X.; Du, H. Palladium-catalyzed asymmetric allylic amination of racemic butadiene monoxide with isatin derivatives. Org. Biomol. Chem. 2015, 13 (20), 5826-5830.
Mao, W.; He, H. H.; Gu, J. Q.; Chen, W.; Wu, K.; Tok, E. S.; Xu, G. Q. Preservation of epoxy groups on surfaces in the covalent attachment of butadiene monoxide on Si(111)-(7x7): the effect of a vinyl substituent. Chem. Commun. 2015, 51 (75), 14195-14198.