Cerium(III) trifluoromethanesulfonate, 98%

Name: Cerium(III) trifluoromethanesulfonate, 98%
SKU: L20251.14

CAS: 76089-77-5 | C3CeF9O9S3 | 587.31 g/mol

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Catalog number L20251.14

also known as L20251-14

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Chemical Identifiers

CAS76089-77-5

IUPAC Namecerium(3+) tritrifluoromethanesulfonate

Molecular FormulaC3CeF9O9S3

InChI KeyPHSMPGGNMIPKTH-UHFFFAOYSA-K

SMILES[Ce+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F

Specifications

Specification Sheet

FormPowder

Elemental AnalysisFluorine F: 28.39 - 29.84%

Assay (unspecified)> 97.5%

Appearance (Color)White

It is employed as intermediate for organic synthesis and pharmaceuticals.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
It is employed as intermediate for organic synthesis and pharmaceuticals.

Solubility
Soluble in water.

Notes
Hygroscopic. store away from water/moisture. Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

RUO – Research Use Only

General References:

Renato Dalpozzo; Antonio De Nino; Loredana Maiuolo; Antonio Procopio; Monica Nardi; Giuseppe Bartoli; Roberto Romeo. Highly efficient and versatile acetylation of alcohols catalyzed by cerium(III) triflate. Tetrahedron Letters. 2003, 30 (44), 5621-5624.
Renato Dalpozzo; Antonio De Nino; Loredana Maiuolo; Antonio Procopio; Antonio Tagarelli; Giovanni Sindona; and Giuseppe Bartoli. II. Simple and Efficient Chemoselective Mild Deprotection of Acetals and Ketals Using Cerium(III) Triflate. J. Org. Chem. 2002, 67 (25), 9093-9095.
Efficient catalyst for acetylation of alcohols with Ac₂O: Tetrahedon Lett., 44, 5621 (2003). The uses of rare-earth metal triflates in organic synthesis have been reviewed by S. Kobayashi: Synlett, 689 (1994); Chem. Rev., 102, 2227 (2002).